Synthesis, crystal structures, magnetic and luminescent properties of unique 1D p-ferrocenylbenzoate-bridged lanthanide complexes

P. F. Yan, F. M. Zhang, G. M. Li, J. W. Zhang, W. B. Sun, M. Suda, Yasuaki Einaga

Research output: Contribution to journal › Article

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Abstract

Treatments of p-ferrocenylbenzoate [p-NaOOCH4C6Fc, Fc=(η5-C5H5)Fe(η5-C 5H4)] with Ln(NO3)3·nH2O afford seven p-ferrocenylbenzoate lanthanide complexes {[Ln(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n [Ln=Ce (1), Pr (2), Sm (3), Eu (4), Gd (5), Tb (6) and Dy (7)]. X-ray crystallographic analysis reveals that the isomorphous complexes {[Ce(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2 ](H3O)}n (1) and {[Pr(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n (2) form a unique 1D double-bridged infinite chain structure bridged by μ2-OOCH4C6Fc groups. Each Ln(III) ion adopts a dodecahedron coordination environment with eight coordinated oxygen atoms from two terminal monodentate coordinated FcC6H4COO- units, two terminal monodentate coordinated H2O molecules and four μ2--OOCH4C6Fc units. The luminescent spectra reveal that only 4 and 6 exhibit characteristic emissions of lanthanide ions, Eu(III) and Tb(III) ions, respectively. The variable-temperature magnetic properties of 5 and 7 suggest that a ferromagnetic coupling between spin carriers may exist in 5.

Original languageEnglish
Pages (from-to)1685-1690
Number of pages6
JournalJournal of Solid State Chemistry
Volume182
Issue number7
DOIs
Publication statusPublished - 2009 Jul

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Lanthanoid Series Elements
Rare earth elements
Crystal structure
Ions
magnetic properties
crystal structure
synthesis
ions
oxygen atoms
Magnetic properties
Oxygen
X rays
Atoms
Molecules
molecules
x rays
Temperature
temperature

Keywords

  • Lanthanide
  • Luminescence
  • Magnetic property
  • P-ferrocenylbenzoate
  • Structures

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry

Cite this

Synthesis, crystal structures, magnetic and luminescent properties of unique 1D p-ferrocenylbenzoate-bridged lanthanide complexes. / Yan, P. F.; Zhang, F. M.; Li, G. M.; Zhang, J. W.; Sun, W. B.; Suda, M.; Einaga, Yasuaki.

In: Journal of Solid State Chemistry, Vol. 182, No. 7, 07.2009, p. 1685-1690.

Research output: Contribution to journal › Article

Yan, PF, Zhang, FM, Li, GM, Zhang, JW, Sun, WB, Suda, M & Einaga, Y 2009, 'Synthesis, crystal structures, magnetic and luminescent properties of unique 1D p-ferrocenylbenzoate-bridged lanthanide complexes', Journal of Solid State Chemistry, vol. 182, no. 7, pp. 1685-1690. https://doi.org/10.1016/j.jssc.2009.01.015
Yan PF, Zhang FM, Li GM, Zhang JW, Sun WB, Suda M et al. Synthesis, crystal structures, magnetic and luminescent properties of unique 1D p-ferrocenylbenzoate-bridged lanthanide complexes. Journal of Solid State Chemistry. 2009 Jul;182(7):1685-1690. https://doi.org/10.1016/j.jssc.2009.01.015
Yan, P. F. ; Zhang, F. M. ; Li, G. M. ; Zhang, J. W. ; Sun, W. B. ; Suda, M. ; Einaga, Yasuaki. / Synthesis, crystal structures, magnetic and luminescent properties of unique 1D p-ferrocenylbenzoate-bridged lanthanide complexes. In: Journal of Solid State Chemistry. 2009 ; Vol. 182, No. 7. pp. 1685-1690.
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abstract = "Treatments of p-ferrocenylbenzoate [p-NaOOCH4C6Fc, Fc=(η5-C5H5)Fe(η5-C 5H4)] with Ln(NO3)3·nH2O afford seven p-ferrocenylbenzoate lanthanide complexes {[Ln(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n [Ln=Ce (1), Pr (2), Sm (3), Eu (4), Gd (5), Tb (6) and Dy (7)]. X-ray crystallographic analysis reveals that the isomorphous complexes {[Ce(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2 ](H3O)}n (1) and {[Pr(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n (2) form a unique 1D double-bridged infinite chain structure bridged by μ2-OOCH4C6Fc groups. Each Ln(III) ion adopts a dodecahedron coordination environment with eight coordinated oxygen atoms from two terminal monodentate coordinated FcC6H4COO- units, two terminal monodentate coordinated H2O molecules and four μ2--OOCH4C6Fc units. The luminescent spectra reveal that only 4 and 6 exhibit characteristic emissions of lanthanide ions, Eu(III) and Tb(III) ions, respectively. The variable-temperature magnetic properties of 5 and 7 suggest that a ferromagnetic coupling between spin carriers may exist in 5.",
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AU - Yan, P. F.

AU - Zhang, F. M.

AU - Li, G. M.

AU - Zhang, J. W.

AU - Sun, W. B.

AU - Suda, M.

AU - Einaga, Yasuaki

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N2 - Treatments of p-ferrocenylbenzoate [p-NaOOCH4C6Fc, Fc=(η5-C5H5)Fe(η5-C 5H4)] with Ln(NO3)3·nH2O afford seven p-ferrocenylbenzoate lanthanide complexes {[Ln(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n [Ln=Ce (1), Pr (2), Sm (3), Eu (4), Gd (5), Tb (6) and Dy (7)]. X-ray crystallographic analysis reveals that the isomorphous complexes {[Ce(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2 ](H3O)}n (1) and {[Pr(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n (2) form a unique 1D double-bridged infinite chain structure bridged by μ2-OOCH4C6Fc groups. Each Ln(III) ion adopts a dodecahedron coordination environment with eight coordinated oxygen atoms from two terminal monodentate coordinated FcC6H4COO- units, two terminal monodentate coordinated H2O molecules and four μ2--OOCH4C6Fc units. The luminescent spectra reveal that only 4 and 6 exhibit characteristic emissions of lanthanide ions, Eu(III) and Tb(III) ions, respectively. The variable-temperature magnetic properties of 5 and 7 suggest that a ferromagnetic coupling between spin carriers may exist in 5.

AB - Treatments of p-ferrocenylbenzoate [p-NaOOCH4C6Fc, Fc=(η5-C5H5)Fe(η5-C 5H4)] with Ln(NO3)3·nH2O afford seven p-ferrocenylbenzoate lanthanide complexes {[Ln(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n [Ln=Ce (1), Pr (2), Sm (3), Eu (4), Gd (5), Tb (6) and Dy (7)]. X-ray crystallographic analysis reveals that the isomorphous complexes {[Ce(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2 ](H3O)}n (1) and {[Pr(OOCH4C6Fc)2(μ2-OOCH 4C6Fc)2(H2O)2] (H3O)}n (2) form a unique 1D double-bridged infinite chain structure bridged by μ2-OOCH4C6Fc groups. Each Ln(III) ion adopts a dodecahedron coordination environment with eight coordinated oxygen atoms from two terminal monodentate coordinated FcC6H4COO- units, two terminal monodentate coordinated H2O molecules and four μ2--OOCH4C6Fc units. The luminescent spectra reveal that only 4 and 6 exhibit characteristic emissions of lanthanide ions, Eu(III) and Tb(III) ions, respectively. The variable-temperature magnetic properties of 5 and 7 suggest that a ferromagnetic coupling between spin carriers may exist in 5.

KW - Lanthanide

KW - Luminescence

KW - Magnetic property

KW - P-ferrocenylbenzoate

KW - Structures

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