Abstract
A one-pot procedure for the synthesis of 2,3,6-trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2, cyclization, and subsequent glycosidation with a glycosyl acceptor 3.
| Original language | English |
|---|---|
| Pages (from-to) | 1833-1836 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 42 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2003 Apr 25 |
| Externally published | Yes |
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Keywords
- Carbohydrates
- Chemoselectivity
- Cyclization
- Glycosylation
- Oligosaccharides
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Synthesis of 2,3,6-trideoxysugar-containing disaccharides by cyclization and glycosidation through the sequential activation of sulfoxide and methylsulfanyl groups in a one-pot procedure. / Amaya, Toru; Takahashi, Daisuke; Tanaka, Hiroshi; Takahashi, Takashi.
In: Angewandte Chemie - International Edition, Vol. 42, No. 16, 25.04.2003, p. 1833-1836.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis of 2,3,6-trideoxysugar-containing disaccharides by cyclization and glycosidation through the sequential activation of sulfoxide and methylsulfanyl groups in a one-pot procedure
AU - Amaya, Toru
AU - Takahashi, Daisuke
AU - Tanaka, Hiroshi
AU - Takahashi, Takashi
PY - 2003/4/25
Y1 - 2003/4/25
N2 - A one-pot procedure for the synthesis of 2,3,6-trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2, cyclization, and subsequent glycosidation with a glycosyl acceptor 3.
AB - A one-pot procedure for the synthesis of 2,3,6-trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2, cyclization, and subsequent glycosidation with a glycosyl acceptor 3.
KW - Carbohydrates
KW - Chemoselectivity
KW - Cyclization
KW - Glycosylation
KW - Oligosaccharides
UR - http://www.scopus.com/inward/record.url?scp=0038031666&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0038031666&partnerID=8YFLogxK
U2 - 10.1002/anie.200250218
DO - 10.1002/anie.200250218
M3 - Article
VL - 42
SP - 1833
EP - 1836
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 16
ER -