Abstract
A one-pot procedure for the synthesis of 2,3,6-trideoxyglycosides 1 has been developed, based on the sequential activation of a sulfoxide group and a methylsulfanyl group in 2, cyclization, and subsequent glycosidation with a glycosyl acceptor 3.
| Original language | English |
|---|---|
| Pages (from-to) | 1833-1836 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 42 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2003 Apr 25 |
| Externally published | Yes |
Keywords
- Carbohydrates
- Chemoselectivity
- Cyclization
- Glycosylation
- Oligosaccharides
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Amaya, T., Takahashi, D., Tanaka, H., & Takahashi, T. (2003). Synthesis of 2,3,6-trideoxysugar-containing disaccharides by cyclization and glycosidation through the sequential activation of sulfoxide and methylsulfanyl groups in a one-pot procedure. Angewandte Chemie - International Edition, 42(16), 1833-1836. https://doi.org/10.1002/anie.200250218