Synthesis of (4ar, 10as)-(—)-8-methoxy-1,1,4a-trimethyl-2-oxo- l,2,3,4,4a,9,10,10a-octahydrophenanthrene, an optically active intermediate for the synthesis of diterpenes

Takeshi Sugai, Hideaki Tojo, Kenji Mori, Kenji Mori

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

(4aR,10aS)-(—)-8-Methoxy-l, l,4a-trimethyl-2-oxo-l,2,3,4,4a,9,10,10a- octahydrophenanthrene, a useful intermediate for the synthesis of optically active diterpenes, was synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone.

Original languageEnglish
Pages (from-to)3127-3132
Number of pages6
JournalAgricultural and Biological Chemistry
Volume50
Issue number12
DOIs
Publication statusPublished - 1986
Externally publishedYes

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Diterpenes
diterpenoids
synthesis

ASJC Scopus subject areas

  • Agricultural and Biological Sciences(all)
  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

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title = "Synthesis of (4ar, 10as)-(—)-8-methoxy-1,1,4a-trimethyl-2-oxo- l,2,3,4,4a,9,10,10a-octahydrophenanthrene, an optically active intermediate for the synthesis of diterpenes",
abstract = "(4aR,10aS)-(—)-8-Methoxy-l, l,4a-trimethyl-2-oxo-l,2,3,4,4a,9,10,10a- octahydrophenanthrene, a useful intermediate for the synthesis of optically active diterpenes, was synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone.",
author = "Takeshi Sugai and Hideaki Tojo and Kenji Mori and Kenji Mori",
year = "1986",
doi = "10.1080/00021369.1986.10867872",
language = "English",
volume = "50",
pages = "3127--3132",
journal = "Bioscience, Biotechnology and Biochemistry",
issn = "0916-8451",
publisher = "Japan Society for Bioscience Biotechnology and Agrochemistry",
number = "12",

}

TY - JOUR

T1 - Synthesis of (4ar, 10as)-(—)-8-methoxy-1,1,4a-trimethyl-2-oxo- l,2,3,4,4a,9,10,10a-octahydrophenanthrene, an optically active intermediate for the synthesis of diterpenes

AU - Sugai, Takeshi

AU - Tojo, Hideaki

AU - Mori, Kenji

AU - Mori, Kenji

PY - 1986

Y1 - 1986

N2 - (4aR,10aS)-(—)-8-Methoxy-l, l,4a-trimethyl-2-oxo-l,2,3,4,4a,9,10,10a- octahydrophenanthrene, a useful intermediate for the synthesis of optically active diterpenes, was synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone.

AB - (4aR,10aS)-(—)-8-Methoxy-l, l,4a-trimethyl-2-oxo-l,2,3,4,4a,9,10,10a- octahydrophenanthrene, a useful intermediate for the synthesis of optically active diterpenes, was synthesized from (S)-3-hydroxy-2,2-dimethylcyclohexanone.

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U2 - 10.1080/00021369.1986.10867872

DO - 10.1080/00021369.1986.10867872

M3 - Article

VL - 50

SP - 3127

EP - 3132

JO - Bioscience, Biotechnology and Biochemistry

JF - Bioscience, Biotechnology and Biochemistry

SN - 0916-8451

IS - 12

ER -