Synthesis of an extended hexagonal molecule as a highly symmetrical ligand

Masayoshi Takase, Atsushi Nakajima, Toshifumi Takeuchi

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

An extended hexagonal molecule that has high symmetry and rigidity was designed and synthesized by a cobalt-catalyzed cyclotrimerization reaction. The ligand possesses six benzoic acids at its periphery, which were connected to a central hexakis(2,5-dodesyloxyphenyl)hexaphenylbenzene core with a maximum intramolecular carboxyl group distance of approximately 3.5 nm.

Original languageEnglish
Pages (from-to)1739-1742
Number of pages4
JournalTetrahedron Letters
Volume46
Issue number10
DOIs
Publication statusPublished - 2005 Mar 7

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Benzoates
Cobalt
Rigidity
Ligands
Molecules

Keywords

  • Cyclotrimerization
  • Hexagonal ligand
  • Supramolecular chemistry
  • Tin porphyrin

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Synthesis of an extended hexagonal molecule as a highly symmetrical ligand. / Takase, Masayoshi; Nakajima, Atsushi; Takeuchi, Toshifumi.

In: Tetrahedron Letters, Vol. 46, No. 10, 07.03.2005, p. 1739-1742.

Research output: Contribution to journalArticle

Takase, Masayoshi ; Nakajima, Atsushi ; Takeuchi, Toshifumi. / Synthesis of an extended hexagonal molecule as a highly symmetrical ligand. In: Tetrahedron Letters. 2005 ; Vol. 46, No. 10. pp. 1739-1742.
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