Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization

Takuya Kochi, Kenji Yoshimura, Kyoko Nozaki

Research output: Contribution to journalArticle

66 Citations (Scopus)

Abstract

The synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization are examined. The methylpalladium complexes are frequently used for mechanistic investigation of the copolymerization. The copolymerization of ethylene and methyl acrylate with the catalysts is examined, and the effects of additives on the catalytic activity are found. The preliminary copolymerization results indicate that further examination of additives, ligands, bases used to prepare the catalysts, and reaction conditions would lead to an improved catalyst system for production of the unique highly linear copolymer of ethylene and methyl acrylate.

Original languageEnglish
Pages (from-to)25-27
Number of pages3
JournalDalton Transactions
Issue number1
DOIs
Publication statusPublished - 2006
Externally publishedYes

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phosphine
Alkenes
Copolymerization
Thermodynamic properties
Polymerization
Ligands
Catalysts
Catalyst activity
Copolymers

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization. / Kochi, Takuya; Yoshimura, Kenji; Nozaki, Kyoko.

In: Dalton Transactions, No. 1, 2006, p. 25-27.

Research output: Contribution to journalArticle

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