Synthesis of aromatic polyketones bearing 1,1'-binaphthyl-2,2'-dioxy units through Suzuki-Miyaura coupling polymerization

Katsuya Maeyama, Tadashi Tsukamoto, Masanori Suzuki, Shuhei Higashibayashi, Hidehiro Sakurai

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Abstract

Palladium nanocluster-catalyzed Suzuki-Miyaura coupling polymerization of 2,2'-bis(iodobenzoylphenoxy)-1,1'-binaphthyls 2 with aromatic diboric acid diesters 3 proceeded smoothly, affording 1,1'-binaphthyl-2,2'-dioxy-bearing aromatic polyketones 4. The resulting polyketones 4 have excellent thermal stability and solubility in typical organic solvents.

Original languageEnglish
Pages (from-to)1445-1446
Number of pages2
JournalChemistry Letters
Volume40
Issue number12
DOIs
Publication statusPublished - 2011 Dec 1

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ASJC Scopus subject areas

  • Chemistry(all)

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