Mesocrystals of Li-Mn-O compounds, such as LiMn2O4, Li2MnO3, and LiMnO2-Li2MnO 3, consisting of oriented nanoscale units were selectively produced under hydrothermal conditions from biomimetically prepared MnCO3 mesocrystals. Topotactic transformation through the intermediate phase of Mn5O8 inheriting a hierarchical structure of the MnCO 3 precursor was essential for the formation of the mesocrystal compounds. The crystal phases were successfully controlled by varying the conditions for the hydrothermal reactions. The Li-Mn-O mesocrystals have considerable potential as cathodes of Li-ion batteries.
ASJC Scopus subject areas
- Materials Science(all)