Synthesis of methoxysilanes by the reaction of metallic silicon with methanol using copper(II) acetate as the catalyst

Masaki Okamoto; Naoki Mimura; Eiichi Suzuki; Yoshio Ono

doi:10.1007/BF00814244

Synthesis of methoxysilanes by the reaction of metallic silicon with methanol using copper(II) acetate as the catalyst

Masaki Okamoto, Naoki Mimura, Eiichi Suzuki, Yoshio Ono

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The reaction of methanol with silicon was studied using various copper compounds other than the halides. Copper(II) acetate and copper(I) oxide gave high silicon conversions (82%) though the selectivities for trimethoxysilane were low (<19%). The selectivity was appreciably improved by addition of a small amount of thiophene or propyl chloride to the methanol feed.

Original language	English
Pages (from-to)	421-427
Number of pages	7
Journal	Catalysis Letters
Volume	33
Issue number	3-4
DOIs	https://doi.org/10.1007/BF00814244
Publication status	Published - 1995 Sept 1
Externally published	Yes

Keywords

copper(II) acetate
methanol
methoxysilanes
silicon

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1007/BF00814244

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abstract = "The reaction of methanol with silicon was studied using various copper compounds other than the halides. Copper(II) acetate and copper(I) oxide gave high silicon conversions (82%) though the selectivities for trimethoxysilane were low (<19%). The selectivity was appreciably improved by addition of a small amount of thiophene or propyl chloride to the methanol feed.",

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author = "Masaki Okamoto and Naoki Mimura and Eiichi Suzuki and Yoshio Ono",

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doi = "10.1007/BF00814244",

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T1 - Synthesis of methoxysilanes by the reaction of metallic silicon with methanol using copper(II) acetate as the catalyst

AU - Okamoto, Masaki

AU - Mimura, Naoki

AU - Suzuki, Eiichi

AU - Ono, Yoshio

PY - 1995/9/1

Y1 - 1995/9/1

N2 - The reaction of methanol with silicon was studied using various copper compounds other than the halides. Copper(II) acetate and copper(I) oxide gave high silicon conversions (82%) though the selectivities for trimethoxysilane were low (<19%). The selectivity was appreciably improved by addition of a small amount of thiophene or propyl chloride to the methanol feed.

AB - The reaction of methanol with silicon was studied using various copper compounds other than the halides. Copper(II) acetate and copper(I) oxide gave high silicon conversions (82%) though the selectivities for trimethoxysilane were low (<19%). The selectivity was appreciably improved by addition of a small amount of thiophene or propyl chloride to the methanol feed.

KW - copper(II) acetate

KW - methanol

KW - methoxysilanes

KW - silicon

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JF - Catalysis Letters

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ER -

Synthesis of methoxysilanes by the reaction of metallic silicon with methanol using copper(II) acetate as the catalyst

Abstract

Keywords

ASJC Scopus subject areas

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