Syntheses of new NHC-sulfonate palladium complexes [N-(2,6- diisopropylphenyl)-N'-sulfomethylNHC] Pd(2,6-lutidine) (7a) and [N-(2,6-diisopropylpheny I)-N' -SulfomethylNHC]Pd(PPhs3) (7b) are reported. The structure of complexes 7a and 7b were determined by single-crystal X-ray analysis as the first examples of bidentate coordination of imidazolium-sulfonate to a metal center.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry