Synthesis of N-heterocyclic carbene-sulfonate palladium complexes

Yusuke Nagai, Takuya Kochi, Kyoko Nozaki

Research output: Contribution to journalArticle

54 Citations (Scopus)

Abstract

Syntheses of new NHC-sulfonate palladium complexes [N-(2,6- diisopropylphenyl)-N'-sulfomethylNHC] Pd(2,6-lutidine) (7a) and [N-(2,6-diisopropylpheny I)-N' -SulfomethylNHC]Pd(PPhs3) (7b) are reported. The structure of complexes 7a and 7b were determined by single-crystal X-ray analysis as the first examples of bidentate coordination of imidazolium-sulfonate to a metal center.

Original languageEnglish
Pages (from-to)6131-6134
Number of pages4
JournalOrganometallics
Volume28
Issue number20
DOIs
Publication statusPublished - 2009 Oct 26
Externally publishedYes

Fingerprint

X ray analysis
Palladium
carbenes
sulfonates
palladium
Metals
Single crystals
synthesis
single crystals
metals
x rays
2,6-lutidine
carbene

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Synthesis of N-heterocyclic carbene-sulfonate palladium complexes. / Nagai, Yusuke; Kochi, Takuya; Nozaki, Kyoko.

In: Organometallics, Vol. 28, No. 20, 26.10.2009, p. 6131-6134.

Research output: Contribution to journalArticle

Nagai, Yusuke ; Kochi, Takuya ; Nozaki, Kyoko. / Synthesis of N-heterocyclic carbene-sulfonate palladium complexes. In: Organometallics. 2009 ; Vol. 28, No. 20. pp. 6131-6134.
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