Synthesis of N-heterocyclic carbene-sulfonate palladium complexes

Yusuke Nagai, Takuya Kochi, Kyoko Nozaki

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Syntheses of new NHC-sulfonate palladium complexes [N-(2,6- diisopropylphenyl)-N'-sulfomethylNHC] Pd(2,6-lutidine) (7a) and [N-(2,6-diisopropylpheny I)-N' -SulfomethylNHC]Pd(PPhs3) (7b) are reported. The structure of complexes 7a and 7b were determined by single-crystal X-ray analysis as the first examples of bidentate coordination of imidazolium-sulfonate to a metal center.

Original languageEnglish
Pages (from-to)6131-6134
Number of pages4
JournalOrganometallics
Volume28
Issue number20
DOIs
Publication statusPublished - 2009 Oct 26
Externally publishedYes

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ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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