Synthesis of novel Hg2+ receptors based on N-benzyloxyamide derivatives and their application to anion-selective electrodes

S. I. Sasaki, T. Amano, S. Ozawa, T. Masuyama, D. Citterio, H. Hisamoto, H. Hori, K. Suzuki

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Novel Hg2+ receptors having two N-benzyloxyamide groups are synthesized, and their complexation ability toward metal cations is examined. The structure of the formed complexes was elucidated by ESI-MS and 1H NMR spectroscopy. Deprotonation of the amide groups allows the receptors to form stable complexes with Hg2+. As an application of this neutral Hg2+ complex, an anion-selective electrode combined with a cationic additive is prepared, and exhibits an anti-Hofmeister selectivity pattern with enhanced selectivity for the iodide anion. The overall selectivity pattern of the electrode is I- > ClO4- > SCN- ≈ Br- > salicylate- > NO2- > Cl- > NO3- ≫ HCO3- > SO42- > F- > H2PO4-.

Original languageEnglish
Pages (from-to)1366-1371
Number of pages6
JournalJournal of the Chemical Society. Perkin Transactions 1
Issue number12
Publication statusPublished - 2001 Jan 1


ASJC Scopus subject areas

  • Chemistry(all)

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