Synthesis of poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate]: Thermal and optical properties of the copolymers with methyl methacrylate

Dingying Zhou; Yasuhiro Koike; Yoshiyuki Okamoto

doi:10.1016/j.jfluchem.2007.11.011

Synthesis of poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate]: Thermal and optical properties of the copolymers with methyl methacrylate

Dingying Zhou, Yasuhiro Koike, Yoshiyuki Okamoto

University

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate (I)] was synthesized, and the copolymers of the monomer I with various compositions of methyl methacrylate (MMA) were prepared and characterized. The glass transition temperature values obtained for the copolymers were between 120 and 150 °C. The refractive indices of the copolymers were in the range of 1.4350-1.4872 at 532 nm. They were thermally stable (up to 297-323 °C), and their water absorptive properties were greatly decreased, compared with pure PMMA.

Original language	English
Pages (from-to)	248-252
Number of pages	5
Journal	Journal of Fluorine Chemistry
Volume	129
Issue number	4
DOIs	https://doi.org/10.1016/j.jfluchem.2007.11.011
Publication status	Published - 2008 Apr

Keywords

Co polymerization
Dipole-dipole interaction
Fluorinated methacrylate
Optical property
Thermal property
Water absorption

ASJC Scopus subject areas

Biochemistry
Environmental Chemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/j.jfluchem.2007.11.011

Cite this

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title = "Synthesis of poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate]: Thermal and optical properties of the copolymers with methyl methacrylate",

abstract = "Poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate (I)] was synthesized, and the copolymers of the monomer I with various compositions of methyl methacrylate (MMA) were prepared and characterized. The glass transition temperature values obtained for the copolymers were between 120 and 150 °C. The refractive indices of the copolymers were in the range of 1.4350-1.4872 at 532 nm. They were thermally stable (up to 297-323 °C), and their water absorptive properties were greatly decreased, compared with pure PMMA.",

keywords = "Co polymerization, Dipole-dipole interaction, Fluorinated methacrylate, Optical property, Thermal property, Water absorption",

author = "Dingying Zhou and Yasuhiro Koike and Yoshiyuki Okamoto",

note = "Funding Information: This work was supported in part by the Japan Science and Technology Corporation through a Grant from ERATO-Sorst Photonic Polymer.",

year = "2008",

month = apr,

doi = "10.1016/j.jfluchem.2007.11.011",

language = "English",

volume = "129",

pages = "248--252",

journal = "Journal of Fluorine Chemistry",

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number = "4",

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TY - JOUR

T1 - Synthesis of poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate]

T2 - Thermal and optical properties of the copolymers with methyl methacrylate

AU - Zhou, Dingying

AU - Koike, Yasuhiro

AU - Okamoto, Yoshiyuki

N1 - Funding Information: This work was supported in part by the Japan Science and Technology Corporation through a Grant from ERATO-Sorst Photonic Polymer.

PY - 2008/4

Y1 - 2008/4

N2 - Poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate (I)] was synthesized, and the copolymers of the monomer I with various compositions of methyl methacrylate (MMA) were prepared and characterized. The glass transition temperature values obtained for the copolymers were between 120 and 150 °C. The refractive indices of the copolymers were in the range of 1.4350-1.4872 at 532 nm. They were thermally stable (up to 297-323 °C), and their water absorptive properties were greatly decreased, compared with pure PMMA.

AB - Poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate (I)] was synthesized, and the copolymers of the monomer I with various compositions of methyl methacrylate (MMA) were prepared and characterized. The glass transition temperature values obtained for the copolymers were between 120 and 150 °C. The refractive indices of the copolymers were in the range of 1.4350-1.4872 at 532 nm. They were thermally stable (up to 297-323 °C), and their water absorptive properties were greatly decreased, compared with pure PMMA.

KW - Co polymerization

KW - Dipole-dipole interaction

KW - Fluorinated methacrylate

KW - Optical property

KW - Thermal property

KW - Water absorption

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U2 - 10.1016/j.jfluchem.2007.11.011

DO - 10.1016/j.jfluchem.2007.11.011

M3 - Article

AN - SCOPUS:40649120912

SN - 0022-1139

VL - 129

SP - 248

EP - 252

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 4

ER -

Synthesis of poly[1,1,1,3,3,3-hexafluoro-2-(pentafluorophenyl)propan-2-yl methacrylate]: Thermal and optical properties of the copolymers with methyl methacrylate

Abstract

Keywords

ASJC Scopus subject areas

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