Synthesis of practical high-gas-barrier carbon films at low and atmospheric pressure for PET bottles

Hideyuki Kodama, Masaki Nakaya, Akira Shirakura, Atsushi Hotta, Terumitsu Hasebe, Tetsuya Suzuki

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

In this paper, the high-gas-barrier properties of a-C:H films are summarized and the possibility of the wider applications of a-C:H films for food and beverage containers is discussed. Coating a-C:H films inside polyethylene terephthalate (PET) bottles dramatically improves the gas barrier property and accordingly, the oxygen transmission rate (OTR) becomes extremely low (∼1/30 of uncoated bottles). In fact, the coating equipment for PET bottles operated by the radio-frequency plasma-enhanced chemical vapor deposition (CVD) method under low pressure has been developed and has already been in practical use. Recently, a unique and cost-effective atmospheric-pressure glow plasma CVD technique was introduced by our group as the substitute for the low-pressure CVD technique. Homogeneous and highly stable plasma was constantly generated under an atmosphere of acetylene gas (C2H2) without using any other dilution gases such as He, Ar and N2. It was found that by using a pulsed power supply operated at a frequency of 35 kHz with a voltage of 24 kV, high gas-barrier a-C:H films were synthesized under atmospheric pressure, which implies that the new power supply would eventually lead to the development of a new atmospheric-pressure glow plasma CVD technique.

Original languageEnglish
Pages (from-to)107-119
Number of pages13
JournalNew Diamond and Frontier Carbon Technology
Volume16
Issue number2
Publication statusPublished - 2006

Fingerprint

Polyethylene Terephthalates
bottles
Carbon films
polyethylene terephthalate
Bottles
Polyethylene terephthalates
Atmospheric pressure
atmospheric pressure
low pressure
Gases
vapor deposition
carbon
synthesis
gases
Plasmas
power supplies
Chemical vapor deposition
luminescence
beverages
coatings

Keywords

  • APG plasma
  • Carbon film
  • DLC
  • Gas barrier
  • PET bottle

ASJC Scopus subject areas

  • Surfaces, Coatings and Films
  • Surfaces and Interfaces
  • Materials Science(all)

Cite this

Synthesis of practical high-gas-barrier carbon films at low and atmospheric pressure for PET bottles. / Kodama, Hideyuki; Nakaya, Masaki; Shirakura, Akira; Hotta, Atsushi; Hasebe, Terumitsu; Suzuki, Tetsuya.

In: New Diamond and Frontier Carbon Technology, Vol. 16, No. 2, 2006, p. 107-119.

Research output: Contribution to journalArticle

Kodama, Hideyuki ; Nakaya, Masaki ; Shirakura, Akira ; Hotta, Atsushi ; Hasebe, Terumitsu ; Suzuki, Tetsuya. / Synthesis of practical high-gas-barrier carbon films at low and atmospheric pressure for PET bottles. In: New Diamond and Frontier Carbon Technology. 2006 ; Vol. 16, No. 2. pp. 107-119.
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