Synthesis of soluble cobaltacyclopentadiene oligomers and polymers

N. Matsuda; T. Shimura; K. Aramaki; H. Nishihara

doi:10.1016/0379-6779(94)02568-J

Synthesis of soluble cobaltacyclopentadiene oligomers and polymers

N. Matsuda, T. Shimura, K. Aramaki, H. Nishihara

Faculty of Law

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Soluble poly(cobaltacyclopentadienylene phenylene) was sythesized by the metallacycling polymerization method using (hexCp)Co(PPh₃)₂ (hexCp = n-hexylcyclopentadienyl) as the starting material. Wavelength of peak edge in its UV-VIS spectra increases with increasing the degree of polymerization, indicating an increase in the average π-conjugation length.

Original language	English
Pages (from-to)	559-560
Number of pages	2
Journal	Synthetic Metals
Volume	69
Issue number	1-3
DOIs	https://doi.org/10.1016/0379-6779(94)02568-J
Publication status	Published - 1995 Mar 1

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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title = "Synthesis of soluble cobaltacyclopentadiene oligomers and polymers",

abstract = "Soluble poly(cobaltacyclopentadienylene phenylene) was sythesized by the metallacycling polymerization method using (hexCp)Co(PPh3)2 (hexCp = n-hexylcyclopentadienyl) as the starting material. Wavelength of peak edge in its UV-VIS spectra increases with increasing the degree of polymerization, indicating an increase in the average π-conjugation length.",

author = "N. Matsuda and T. Shimura and K. Aramaki and H. Nishihara",

note = "Funding Information: ACKNOWLEDGEMENTS This work was partly supported by a Grant-in-Aid for Scientific Research No. 06226274 from the Ministry of Education, Science and Culture of Japan, and a Iketani Research Grant.",

year = "1995",

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doi = "10.1016/0379-6779(94)02568-J",

language = "English",

volume = "69",

pages = "559--560",

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T1 - Synthesis of soluble cobaltacyclopentadiene oligomers and polymers

AU - Matsuda, N.

AU - Shimura, T.

AU - Aramaki, K.

AU - Nishihara, H.

N1 - Funding Information: ACKNOWLEDGEMENTS This work was partly supported by a Grant-in-Aid for Scientific Research No. 06226274 from the Ministry of Education, Science and Culture of Japan, and a Iketani Research Grant.

PY - 1995/3/1

Y1 - 1995/3/1

N2 - Soluble poly(cobaltacyclopentadienylene phenylene) was sythesized by the metallacycling polymerization method using (hexCp)Co(PPh3)2 (hexCp = n-hexylcyclopentadienyl) as the starting material. Wavelength of peak edge in its UV-VIS spectra increases with increasing the degree of polymerization, indicating an increase in the average π-conjugation length.

AB - Soluble poly(cobaltacyclopentadienylene phenylene) was sythesized by the metallacycling polymerization method using (hexCp)Co(PPh3)2 (hexCp = n-hexylcyclopentadienyl) as the starting material. Wavelength of peak edge in its UV-VIS spectra increases with increasing the degree of polymerization, indicating an increase in the average π-conjugation length.

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DO - 10.1016/0379-6779(94)02568-J

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VL - 69

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EP - 560

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1-3

ER -

Synthesis of soluble cobaltacyclopentadiene oligomers and polymers

Abstract

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