Synthesis of substituted sumanenes by aromatic electrophilic substitution reactions

Binod Babu Shrestha; Sangita Karanjit; Gautam Panda; Shuhei Higashibayashi; Hidehiro Sakurai

doi:10.1246/cl.121273

Synthesis of substituted sumanenes by aromatic electrophilic substitution reactions

Binod Babu Shrestha, Sangita Karanjit, Gautam Panda, Shuhei Higashibayashi, Hidehiro Sakurai

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.

Original language	English
Pages (from-to)	386-388
Number of pages	3
Journal	Chemistry Letters
Volume	42
Issue number	4
DOIs	https://doi.org/10.1246/cl.121273
Publication status	Published - 2013 Apr 15
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "Synthesis of substituted sumanenes by aromatic electrophilic substitution reactions",

abstract = "Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.",

author = "Shrestha, {Binod Babu} and Sangita Karanjit and Gautam Panda and Shuhei Higashibayashi and Hidehiro Sakurai",

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AU - Karanjit, Sangita

AU - Panda, Gautam

AU - Higashibayashi, Shuhei

AU - Sakurai, Hidehiro

PY - 2013/4/15

Y1 - 2013/4/15

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AB - Electrophilic substitution reactions of sumanene were studied. Mono-, di-, and trisubstituted sumanenes were selectively prepared with the separation of all regioisomers. The regioselectivity was predicted well by the HOMO density values determined by DFT calculations.

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