Synthesis of triaryltriazasumanenes

Patcharin Kaewmati, Qitao Tan, Shuhei Higashibayashi, Yumi Yakiyama, Hidehiro Sakurai

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

C3-symmetric chiral triaryltriazasumanenes were successfully prepared in good yields by Pd-catalyzed cross-coupling reactions of chiral tris(methylthio)triazasumanene with various arylboronic acids. These chiral triaryltriazasumanenes showed very stable bowl chirality without racemization at room temperature. Single-crystal X-ray crystallography of the p-(trifluoromethyl)phenyl derivative revealed the formation of unidirectional π-π stacking columns that were connected by F⋯F interactions unlike the noncolumnar crystal packing of tris(methanesulfonyl)triazasumanene.

Original languageEnglish
Pages (from-to)146-148
Number of pages3
JournalChemistry Letters
Volume46
Issue number1
DOIs
Publication statusPublished - 2017
Externally publishedYes

Keywords

  • Pd-catalyzed cross coupling
  • Triazasumanene
  • Unidirectional columnar packing

ASJC Scopus subject areas

  • Chemistry(all)

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  • Cite this

    Kaewmati, P., Tan, Q., Higashibayashi, S., Yakiyama, Y., & Sakurai, H. (2017). Synthesis of triaryltriazasumanenes. Chemistry Letters, 46(1), 146-148. https://doi.org/10.1246/cl.160978