Synthesis, structure, and optical properties of SiO2-Gd 2O3:Eu3+ nanocomposite thin films

Shinnosuke Koji, Shinobu Fujihara

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Abstract

SiO2-Gd2O3:Eu3+ nanocomposite thin films were successfully synthesized by a sol-gel method. Precursor solutions were prepared by mixing aqueous rare-earth acetate solutions and ethanolic tetraethylortbosilicate solutions containing trifluoroacetic acid and N,N-dimethylformamide, respectively. The solutions were then spin-coated on silica glass substrates and heat-treated. Two kinds of heat-treatment processes were adopted; one involved heating the coated substrates immediately at temperatures of 700-1000°C, and the other involved preheating them at 300°C, followed by heating at 700-1000°C. In the latter process, denoted a two-step process, SiO2-GdF3 composite films formed at 300°C were pyrolytically converted into SiO2-Gd 2O3 nanocomposite films at the higher heating temperatures. This process was effective in enhancing the crystallinity of Gd2O3. Observations of the structure and luminescent properties of die films revealed that Eu3+ ions were incorporated into cubic-type Gd2O3 nanocrystals that were surrounded by the silica matrix. As a result, efficient red emissions at approximately 610 nm were produced from Eu3+ in response to a UV light excitation at 256 nm.

Original languageEnglish
Pages (from-to)H249-H253
JournalJournal of the Electrochemical Society
Volume151
Issue number12
DOIs
Publication statusPublished - 2004 Dec 1

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ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Surfaces, Coatings and Films
  • Electrochemistry
  • Materials Chemistry

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