Synthetic studies on altohyrtins (spongistatins): Synthesis of the C1- C14 (AB) spiroacetal portion

Takeshi Terauchi, Masaya Nakata

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The C1-C14 portion of altohyrtins (spongistatins) was prepared in a convergent manner from 3,4,6-tri-O-acetyl-D-glucal via a chelation-controlled methylation of ketone, dithiane couplings with epoxides, and a thermodynamically-controlled spitoacetalization.

Original languageEnglish
Pages (from-to)3795-3798
Number of pages4
JournalTetrahedron Letters
Volume39
Issue number22
DOIs
Publication statusPublished - 1998 May 28

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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