Synthetic studies on biscembranoids: Asymmetric total synthesis of methyl sarcoate

Takahiro Ichige, Satoshi Kamimura, Kazuya Mayumi, Yasuyuki Sakamoto, Shingo Terashita, Eriko Ohteki, Naoki Kanoh, Masaya Nakata

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

The asymmetric total synthesis of a marine natural product, methyl sarcoate, has been achieved featuring the asymmetric Michael addition, the dithiane coupling, the Kosugi-Migita-Stille coupling, and the ring-closing metathesis.

Original languageEnglish
Pages (from-to)1263-1267
Number of pages5
JournalTetrahedron Letters
Volume46
Issue number8
DOIs
Publication statusPublished - 2005 Feb 21

Keywords

  • Biscembranoid
  • Dithiane
  • Kosugi-Migita-Stille coupling
  • Methyl sarcoate
  • Ring-closing metathesis

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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  • Cite this

    Ichige, T., Kamimura, S., Mayumi, K., Sakamoto, Y., Terashita, S., Ohteki, E., Kanoh, N., & Nakata, M. (2005). Synthetic studies on biscembranoids: Asymmetric total synthesis of methyl sarcoate. Tetrahedron Letters, 46(8), 1263-1267. https://doi.org/10.1016/j.tetlet.2004.12.132