Synthetic studies towards pentacyclic quassinoids: Facile and stereocontrolled construction of the E ring

Tony K.M. Shing; Xue Y. Zhu; Thomas C.W. Mak

doi:10.1016/0957-4166(96)00062-6

Synthetic studies towards pentacyclic quassinoids: Facile and stereocontrolled construction of the E ring

Tony K.M. Shing, Xue Y. Zhu, Thomas C.W. Mak

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The CE ring 15 of the pentacyclic quassinoid skeleton is fabricated from (S)-carvone involving regioselective bishydroxylmethylation, acetonation, stereocontrolled epoxidation and epoxymethano-bridge formation, selective protection, deprotection, and oxidation.

Original language	English
Pages (from-to)	673-676
Number of pages	4
Journal	Tetrahedron Asymmetry
Volume	7
Issue number	3
DOIs	https://doi.org/10.1016/0957-4166(96)00062-6
Publication status	Published - 1996 Mar 21

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1016/0957-4166(96)00062-6

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title = "Synthetic studies towards pentacyclic quassinoids: Facile and stereocontrolled construction of the E ring",

abstract = "The CE ring 15 of the pentacyclic quassinoid skeleton is fabricated from (S)-carvone involving regioselective bishydroxylmethylation, acetonation, stereocontrolled epoxidation and epoxymethano-bridge formation, selective protection, deprotection, and oxidation.",

author = "Shing, {Tony K.M.} and Zhu, {Xue Y.} and Mak, {Thomas C.W.}",

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AU - Zhu, Xue Y.

AU - Mak, Thomas C.W.

PY - 1996/3/21

Y1 - 1996/3/21

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AB - The CE ring 15 of the pentacyclic quassinoid skeleton is fabricated from (S)-carvone involving regioselective bishydroxylmethylation, acetonation, stereocontrolled epoxidation and epoxymethano-bridge formation, selective protection, deprotection, and oxidation.

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Synthetic studies towards pentacyclic quassinoids: Facile and stereocontrolled construction of the E ring

Abstract

ASJC Scopus subject areas

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