Synthetic study towards the tetracyclic quassinoid skeleton

Tony K.M. Shing; Tang Ying

doi:10.1016/S0040-4020(01)89783-0

Synthetic study towards the tetracyclic quassinoid skeleton

Tony K.M. Shing, Tang Ying

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The optically active tetracycle (6) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone in 9 steps involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction.

Original language	English
Pages (from-to)	2187-2194
Number of pages	8
Journal	Tetrahedron
Volume	46
Issue number	6
DOIs	https://doi.org/10.1016/S0040-4020(01)89783-0
Publication status	Published - 1990

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4020(01)89783-0

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title = "Synthetic study towards the tetracyclic quassinoid skeleton",

abstract = "The optically active tetracycle (6) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone in 9 steps involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction.",

author = "Shing, {Tony K.M.} and Tang Ying",

year = "1990",

doi = "10.1016/S0040-4020(01)89783-0",

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AU - Ying, Tang

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AB - The optically active tetracycle (6) with two trans-fused angular methyl groups is constructed from tiglic aldehyde and (S)-carvone in 9 steps involving a stereocontrolled aldol reaction and an endo-selective intramolecular Diels-Alder (IMDA) reaction.

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U2 - 10.1016/S0040-4020(01)89783-0

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JO - Tetrahedron

JF - Tetrahedron

IS - 6

ER -

Synthetic study towards the tetracyclic quassinoid skeleton

Abstract

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