Temperature-dependent photocarrier recombination dynamics in Cu 2ZnSnS4 single crystals

Le Quang Phuong, Makoto Okano, Yasuhiro Yamada, Akira Nagaoka, Kenji Yoshino, Yoshihiko Kanemitsu

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Time-resolved photoluminescence (PL) measurements have been used to study the temperature-dependent photocarrier recombination dynamics in Cu 2ZnSnS4 (CZTS) single crystals. We found a significant change of nearly four orders of magnitude of the PL decay time, from microseconds at low temperatures to subnanoseconds at room temperature. The slow PL decay at low temperatures indicates localization of the photocarriers at the band tails. Due to the large band tail states, the PL decay time depends strongly on both the photon energy and excitation density. It is pointed out that the drastically enhanced nonradiative recombination at high temperatures is one of the main factors that determine the power conversion efficiency of CZTS-based solar cells.

Original languageEnglish
Article number81907
JournalApplied Physics Letters
Volume104
Issue number8
DOIs
Publication statusPublished - 2014
Externally publishedYes

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photoluminescence
single crystals
decay
temperature
flux density
solar cells
photons
room temperature
excitation

ASJC Scopus subject areas

  • Physics and Astronomy (miscellaneous)

Cite this

Temperature-dependent photocarrier recombination dynamics in Cu 2ZnSnS4 single crystals. / Phuong, Le Quang; Okano, Makoto; Yamada, Yasuhiro; Nagaoka, Akira; Yoshino, Kenji; Kanemitsu, Yoshihiko.

In: Applied Physics Letters, Vol. 104, No. 8, 81907, 2014.

Research output: Contribution to journalArticle

Phuong, Le Quang ; Okano, Makoto ; Yamada, Yasuhiro ; Nagaoka, Akira ; Yoshino, Kenji ; Kanemitsu, Yoshihiko. / Temperature-dependent photocarrier recombination dynamics in Cu 2ZnSnS4 single crystals. In: Applied Physics Letters. 2014 ; Vol. 104, No. 8.
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