The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step

Naoto Chatani, Tamotsu Kodama, Yasuteru Kajikawa, Hidetatsu Murakami, Fumitoshi Kakiuchi, Shin Ichi Ikeda, Shinji Murai

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Abstract

The hydrosilylation of oxygen-containing olefins in the presence of Co2(CO)8 was carried out. The Co2(CO)8-catalyzed hydrosilylation of allyl acetate with HSiEt2Me is consistent with proceeding via a silylmetalation mechanism rather than a classical hydrometalation (Chalk-Harrod mechanism).

Original languageEnglish
Pages (from-to)14-15
Number of pages2
JournalChemistry Letters
Issue number1
Publication statusPublished - 2000
Externally publishedYes

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ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Chatani, N., Kodama, T., Kajikawa, Y., Murakami, H., Kakiuchi, F., Ikeda, S. I., & Murai, S. (2000). The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step. Chemistry Letters, (1), 14-15.