The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step

Naoto Chatani, Tamotsu Kodama, Yasuteru Kajikawa, Hidetatsu Murakami, Fumitoshi Kakiuchi, Shin Ichi Ikeda, Shinji Murai

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

The hydrosilylation of oxygen-containing olefins in the presence of Co2(CO)8 was carried out. The Co2(CO)8-catalyzed hydrosilylation of allyl acetate with HSiEt2Me is consistent with proceeding via a silylmetalation mechanism rather than a classical hydrometalation (Chalk-Harrod mechanism).

Original languageEnglish
Pages (from-to)14-15
Number of pages2
JournalChemistry Letters
Issue number1
Publication statusPublished - 2000
Externally publishedYes

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Hydrosilylation
Alkenes
Oxygen
Calcium Carbonate
allyl acetate

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Chatani, N., Kodama, T., Kajikawa, Y., Murakami, H., Kakiuchi, F., Ikeda, S. I., & Murai, S. (2000). The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step. Chemistry Letters, (1), 14-15.

The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins : Silylmetalation as a key step. / Chatani, Naoto; Kodama, Tamotsu; Kajikawa, Yasuteru; Murakami, Hidetatsu; Kakiuchi, Fumitoshi; Ikeda, Shin Ichi; Murai, Shinji.

In: Chemistry Letters, No. 1, 2000, p. 14-15.

Research output: Contribution to journalArticle

Chatani, N, Kodama, T, Kajikawa, Y, Murakami, H, Kakiuchi, F, Ikeda, SI & Murai, S 2000, 'The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step', Chemistry Letters, no. 1, pp. 14-15.
Chatani, Naoto ; Kodama, Tamotsu ; Kajikawa, Yasuteru ; Murakami, Hidetatsu ; Kakiuchi, Fumitoshi ; Ikeda, Shin Ichi ; Murai, Shinji. / The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins : Silylmetalation as a key step. In: Chemistry Letters. 2000 ; No. 1. pp. 14-15.
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