The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step

Naoto Chatani; Tamotsu Kodama; Yasuteru Kajikawa; Hidetatsu Murakami; Fumitoshi Kakiuchi; Shin Ichi Ikeda; Shinji Murai

doi:10.1246/cl.2000.14

The Co₂(CO)₈-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step

Naoto Chatani, Tamotsu Kodama, Yasuteru Kajikawa, Hidetatsu Murakami, Fumitoshi Kakiuchi, Shin Ichi Ikeda, Shinji Murai

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

The hydrosilylation of oxygen-containing olefins in the presence of Co₂(CO)₈ was carried out. The Co₂(CO)₈-catalyzed hydrosilylation of allyl acetate with HSiEt₂Me is consistent with proceeding via a silylmetalation mechanism rather than a classical hydrometalation (Chalk-Harrod mechanism).

Original language	English
Pages (from-to)	14-15
Number of pages	2
Journal	Chemistry Letters
Issue number	1
DOIs	https://doi.org/10.1246/cl.2000.14
Publication status	Published - 2000
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)

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title = "The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step",

abstract = "The hydrosilylation of oxygen-containing olefins in the presence of Co2(CO)8 was carried out. The Co2(CO)8-catalyzed hydrosilylation of allyl acetate with HSiEt2Me is consistent with proceeding via a silylmetalation mechanism rather than a classical hydrometalation (Chalk-Harrod mechanism).",

author = "Naoto Chatani and Tamotsu Kodama and Yasuteru Kajikawa and Hidetatsu Murakami and Fumitoshi Kakiuchi and Ikeda, {Shin Ichi} and Shinji Murai",

note = "Funding Information: The authors acknowledge the financial support provided by PROMEP, CONACyT and DGEST, Mexico.",

year = "2000",

doi = "10.1246/cl.2000.14",

language = "English",

pages = "14--15",

journal = "Chemistry Letters",

issn = "0366-7022",

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T1 - The Co2(CO)8-catalyzed hydrosilylation of oxygen-containing olefins

T2 - Silylmetalation as a key step

AU - Chatani, Naoto

AU - Kodama, Tamotsu

AU - Kajikawa, Yasuteru

AU - Murakami, Hidetatsu

AU - Kakiuchi, Fumitoshi

AU - Ikeda, Shin Ichi

AU - Murai, Shinji

N1 - Funding Information: The authors acknowledge the financial support provided by PROMEP, CONACyT and DGEST, Mexico.

PY - 2000

Y1 - 2000

N2 - The hydrosilylation of oxygen-containing olefins in the presence of Co2(CO)8 was carried out. The Co2(CO)8-catalyzed hydrosilylation of allyl acetate with HSiEt2Me is consistent with proceeding via a silylmetalation mechanism rather than a classical hydrometalation (Chalk-Harrod mechanism).

AB - The hydrosilylation of oxygen-containing olefins in the presence of Co2(CO)8 was carried out. The Co2(CO)8-catalyzed hydrosilylation of allyl acetate with HSiEt2Me is consistent with proceeding via a silylmetalation mechanism rather than a classical hydrometalation (Chalk-Harrod mechanism).

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U2 - 10.1246/cl.2000.14

DO - 10.1246/cl.2000.14

M3 - Article

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JO - Chemistry Letters

JF - Chemistry Letters

IS - 1

ER -

The Co₂(CO)₈-catalyzed hydrosilylation of oxygen-containing olefins: Silylmetalation as a key step

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