The influence of additives on lithium dope / undope reactions for a tin film electrode in a room-temperature ionic liquid electrolyte

Soudai Miyashita; Yasushi Katayama; Takashi Miura; Shin Ichi Komaba

doi:10.1149/1.3393853

The influence of additives on lithium dope / undope reactions for a tin film electrode in a room-temperature ionic liquid electrolyte

Soudai Miyashita, Yasushi Katayama, Takashi Miura, Shin Ichi Komaba

Department of Applied Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

1 Citation (Scopus)

Abstract

Limium dope-undope reactions of a tin thin film electrode were investigated in a room-temperature ionic liquid, 1-butyl-1-memyl-pyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing 1 M LiTFSA with and without glyme as an additive. Lithium dope-undope was possible in 1 M LiTFSA/BMPTFSA with glymes. The resistance of the electrode-electrolyte interface with glyme was smaller man that without glyme, indicating the solvation environment of Li⁺ affects me interfacial resistance in the ionic liquid electrolyte.

Original language	English
Title of host publication	Rechargeable Lithium-Ion Batteries
Publisher	Electrochemical Society Inc.
Pages	169-176
Number of pages	8
Edition	36
ISBN (Electronic)	9781566778107
ISBN (Print)	9781566778107
DOIs	https://doi.org/10.1149/1.3393853
Publication status	Published - 2009

Publication series

Name	ECS Transactions
Number	36
Volume	25
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

ASJC Scopus subject areas

Engineering(all)

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10.1149/1.3393853

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The influence of additives on lithium dope / undope reactions for a tin film electrode in a room-temperature ionic liquid electrolyte. / Miyashita, Soudai; Katayama, Yasushi; Miura, Takashi et al.
Rechargeable Lithium-Ion Batteries. 36. ed. Electrochemical Society Inc., 2009. p. 169-176 (ECS Transactions; Vol. 25, No. 36).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

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AB - Limium dope-undope reactions of a tin thin film electrode were investigated in a room-temperature ionic liquid, 1-butyl-1-memyl-pyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) containing 1 M LiTFSA with and without glyme as an additive. Lithium dope-undope was possible in 1 M LiTFSA/BMPTFSA with glymes. The resistance of the electrode-electrolyte interface with glyme was smaller man that without glyme, indicating the solvation environment of Li+ affects me interfacial resistance in the ionic liquid electrolyte.

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The influence of additives on lithium dope / undope reactions for a tin film electrode in a room-temperature ionic liquid electrolyte

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