The infrared HOMO-LUMO gap of germanium clusters

Y. Negishi, H. Kawamata, F. Hayakawa, A. Nakajima, K. Kaya

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

The electronic structures of germanium cluster (Gen; n=4-32) were studied by using photoelectron spectroscopy (PES) for Gen-, GenF-, and GenCl-. The halogen atom doping method enables us to determine the HOMO-LUMO gap of the corresponding neutral Gen cluster to be 0.8-1.0 eV around n=30. This result implies that the Gen cluster itself never emits visible emissions.

Original languageEnglish
Pages (from-to)370-376
Number of pages7
JournalChemical Physics Letters
Volume294
Issue number4-5
DOIs
Publication statusPublished - 1998 Sep 18

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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