The reactivity of superoxide: A potent oxidant generated in situ from superoxide and CO2

Hiroshi Yamamoto; Tadahiko Mashino; Tetsuo Nagano; Masaaki Hirobe

doi:10.1016/S0040-4039(00)99341-9

The reactivity of superoxide: A potent oxidant generated in situ from superoxide and CO₂

Hiroshi Yamamoto, Tadahiko Mashino, Tetsuo Nagano, Masaaki Hirobe

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The reaction of CO₂ with superoxide cooxidized sulfides and olefins to the corresponding sulfoxides and epoxides, respectively, in dimethylformamide. The peroxy intermediates, CO₄??? and C₂O₆???, generated in situ from superoxide and CO₂, were proposed as the ultimate oxidants in the oxidations.

Original language	English
Pages (from-to)	4133-4136
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(00)99341-9
Publication status	Published - 1989
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

Access to Document

10.1016/S0040-4039(00)99341-9

Cite this

@article{43a44e8d6b9c42449922ed5ff1bebc93,

title = "The reactivity of superoxide: A potent oxidant generated in situ from superoxide and CO2",

abstract = "The reaction of CO2 with superoxide cooxidized sulfides and olefins to the corresponding sulfoxides and epoxides, respectively, in dimethylformamide. The peroxy intermediates, CO4??? and C2O6???, generated in situ from superoxide and CO2, were proposed as the ultimate oxidants in the oxidations.",

author = "Hiroshi Yamamoto and Tadahiko Mashino and Tetsuo Nagano and Masaaki Hirobe",

year = "1989",

doi = "10.1016/S0040-4039(00)99341-9",

language = "English",

volume = "30",

pages = "4133--4136",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "31",

}

TY - JOUR

T1 - The reactivity of superoxide

T2 - A potent oxidant generated in situ from superoxide and CO2

AU - Yamamoto, Hiroshi

AU - Mashino, Tadahiko

AU - Nagano, Tetsuo

AU - Hirobe, Masaaki

PY - 1989

Y1 - 1989

N2 - The reaction of CO2 with superoxide cooxidized sulfides and olefins to the corresponding sulfoxides and epoxides, respectively, in dimethylformamide. The peroxy intermediates, CO4??? and C2O6???, generated in situ from superoxide and CO2, were proposed as the ultimate oxidants in the oxidations.

AB - The reaction of CO2 with superoxide cooxidized sulfides and olefins to the corresponding sulfoxides and epoxides, respectively, in dimethylformamide. The peroxy intermediates, CO4??? and C2O6???, generated in situ from superoxide and CO2, were proposed as the ultimate oxidants in the oxidations.

UR - http://www.scopus.com/inward/record.url?scp=0343894591&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0343894591&partnerID=8YFLogxK

U2 - 10.1016/S0040-4039(00)99341-9

DO - 10.1016/S0040-4039(00)99341-9

M3 - Article

AN - SCOPUS:0343894591

SN - 0040-4039

VL - 30

SP - 4133

EP - 4136

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

The reactivity of superoxide: A potent oxidant generated in situ from superoxide and CO₂

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this