The RuH2(CO)(PPh3)3-catalysed alkylation, alkenylation, and arylation of aromatic ketones via carbon-hydrogen bond cleavage

Fumitoshi Kakiuchi, Satoshi Ueno, Naoto Chatani

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

The RuH2(CO)(PPh3)3-catalysed alkylation, alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage Catalytic, asymmetric synthesis of a, a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts.

Original languageEnglish
Title of host publicationCatalysts for Fine Chemical Synthesis
Subtitle of host publicationMetal Catalysed Carbon-Carbon Bond-Forming Reactions
Publisherwiley
Pages14-21
Number of pages8
Volume3
ISBN (Electronic)9780470862018
ISBN (Print)9780470861998
DOIs
Publication statusPublished - 2005 Jan 1
Externally publishedYes

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Keywords

  • Carbon-hydrogen bond conversion
  • Carbon-hydrogen bond-activation
  • Catalytic functionalisation
  • New carbon-carbon bond
  • Transition metal complexes
  • Unreactive carbon-hydrogen bond cleavage

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Kakiuchi, F., Ueno, S., & Chatani, N. (2005). The RuH2(CO)(PPh3)3-catalysed alkylation, alkenylation, and arylation of aromatic ketones via carbon-hydrogen bond cleavage. In Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions (Vol. 3, pp. 14-21). wiley. https://doi.org/10.1002/0470862017.ch2