The RuH2(CO)(PPh3)3-catalysed alkylation, alkenylation, and arylation of aromatic ketones via carbon-hydrogen bond cleavage

Fumitoshi Kakiuchi; Satoshi Ueno; Naoto Chatani

doi:10.1002/0470862017.ch2

The RuH₂(CO)(PPh₃)₃-catalysed alkylation, alkenylation, and arylation of aromatic ketones via carbon-hydrogen bond cleavage

Fumitoshi Kakiuchi, Satoshi Ueno, Naoto Chatani

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

The RuH₂(CO)(PPh₃)₃-catalysed alkylation, alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage Catalytic, asymmetric synthesis of a, a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts.

Original language	English
Title of host publication	Catalysts for Fine Chemical Synthesis
Subtitle of host publication	Metal Catalysed Carbon-Carbon Bond-Forming Reactions
Publisher	wiley
Pages	14-21
Number of pages	8
Volume	3
ISBN (Electronic)	9780470862018
ISBN (Print)	9780470861998
DOIs	https://doi.org/10.1002/0470862017.ch2
Publication status	Published - 2005 Jan 1
Externally published	Yes

Keywords

Carbon-hydrogen bond conversion
Carbon-hydrogen bond-activation
Catalytic functionalisation
New carbon-carbon bond
Transition metal complexes
Unreactive carbon-hydrogen bond cleavage

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/0470862017.ch2

Cite this

The RuH₂(CO)(PPh₃)₃-catalysed alkylation, alkenylation, and arylation of aromatic ketones via carbon-hydrogen bond cleavage. / Kakiuchi, Fumitoshi; Ueno, Satoshi; Chatani, Naoto.

Catalysts for Fine Chemical Synthesis: Metal Catalysed Carbon-Carbon Bond-Forming Reactions. Vol. 3 wiley, 2005. p. 14-21.

Research output: Chapter in Book/Report/Conference proceeding › Chapter

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abstract = "The RuH2(CO)(PPh3)3-catalysed alkylation, alkenylation and arylation of aromatic ketones via carbon-hydrogen bond cleavage Catalytic, asymmetric synthesis of a, a-disubstituted amino acids using a chiral copper-salen complex as a phase transfer catalyst Asymmetric phase-transfer catalysed alkylation of glycine imines using cinchona alkaloid derived quaternary ammonium salts.",

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