The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins

Fumitoshi Kakiuchi, Taisuke Sato, Kimitaka Igi, Naoto Chatani, Shinji Murai

Research output: Contribution to journalArticle

85 Citations (Scopus)

Abstract

The addition of a β C-H bond to the formyl group of aldehydes to olefins took place with the aid of Ru(H)2(CO)(PPh3)3 as a catalyst. Several olefins can be used in the catalytic reaction of conjugate enals. The presence of a sterically hindered substituent at the ortho position of benzaldehyde and the presence of an electron donating substituent appear to be important factor in accomplishing the desired coupling reaction.

Original languageEnglish
Pages (from-to)386-387
Number of pages2
JournalChemistry Letters
Issue number5
Publication statusPublished - 2001
Externally publishedYes

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Ruthenium
Alkenes
Aldehydes
Carbon Monoxide
Catalysts
Electrons
benzaldehyde

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Kakiuchi, F., Sato, T., Igi, K., Chatani, N., & Murai, S. (2001). The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins. Chemistry Letters, (5), 386-387.

The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins. / Kakiuchi, Fumitoshi; Sato, Taisuke; Igi, Kimitaka; Chatani, Naoto; Murai, Shinji.

In: Chemistry Letters, No. 5, 2001, p. 386-387.

Research output: Contribution to journalArticle

Kakiuchi, F, Sato, T, Igi, K, Chatani, N & Murai, S 2001, 'The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins', Chemistry Letters, no. 5, pp. 386-387.
Kakiuchi, Fumitoshi ; Sato, Taisuke ; Igi, Kimitaka ; Chatani, Naoto ; Murai, Shinji. / The ruthenium-catalyzed addition of β C-H bonds in aldehydes to olefins. In: Chemistry Letters. 2001 ; No. 5. pp. 386-387.
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