The stereochemistry of the epoxypropyl side-chain of asperlin

Tony K.M. Shing; M. Aloui

doi:10.1039/C39880001525

The stereochemistry of the epoxypropyl side-chain of asperlin

Tony K.M. Shing, M. Aloui

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The absolute configuration of the oxirane moiety in asperlin is shown to be (6S,7R) by an unambiguous synthesis of its (6R,7S)-diastereoisomer from D-glucose involving a tandem epoxide formation and intramolecular Wadsworth-Emmons-Horner olefination.

Original language	English
Pages (from-to)	1525-1526
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	23
DOIs	https://doi.org/10.1039/C39880001525
Publication status	Published - 1988
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "The stereochemistry of the epoxypropyl side-chain of asperlin",

abstract = "The absolute configuration of the oxirane moiety in asperlin is shown to be (6S,7R) by an unambiguous synthesis of its (6R,7S)-diastereoisomer from D-glucose involving a tandem epoxide formation and intramolecular Wadsworth-Emmons-Horner olefination.",

author = "Shing, {Tony K.M.} and M. Aloui",

year = "1988",

doi = "10.1039/C39880001525",

language = "English",

pages = "1525--1526",

journal = "Chemical Communications",

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AU - Shing, Tony K.M.

AU - Aloui, M.

PY - 1988

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AB - The absolute configuration of the oxirane moiety in asperlin is shown to be (6S,7R) by an unambiguous synthesis of its (6R,7S)-diastereoisomer from D-glucose involving a tandem epoxide formation and intramolecular Wadsworth-Emmons-Horner olefination.

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DO - 10.1039/C39880001525

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SP - 1525

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JO - Chemical Communications

JF - Chemical Communications

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ER -

The stereochemistry of the epoxypropyl side-chain of asperlin

Abstract

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