The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt, Berit Topolinski, Shuhei Higashibayashi, Tatsuhiro Kojima, Masaki Kawano, Dieter Lentz, Hidehiro Sakurai

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

Original languageEnglish
Pages (from-to)3282-3286
Number of pages5
JournalChemistry - A European Journal
Volume19
Issue number10
DOIs
Publication statusPublished - 2013 Mar 4
Externally publishedYes

Keywords

  • buckybowls
  • crystal engineering
  • fluorine
  • pi interactions
  • sumanene

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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  • Cite this

    Schmidt, B. M., Topolinski, B., Higashibayashi, S., Kojima, T., Kawano, M., Lentz, D., & Sakurai, H. (2013). The synthesis of hexafluorosumanene and its congeners. Chemistry - A European Journal, 19(10), 3282-3286. https://doi.org/10.1002/chem.201204622