The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt, Berit Topolinski, Shuhei Higashibayashi, Tatsuhiro Kojima, Masaki Kawano, Dieter Lentz, Hidehiro Sakurai

Research output: Contribution to journalArticle

24 Citations (Scopus)

Abstract

Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

Original languageEnglish
Pages (from-to)3282-3286
Number of pages5
JournalChemistry - A European Journal
Volume19
Issue number10
DOIs
Publication statusPublished - 2013 Mar 4
Externally publishedYes

Fingerprint

Gems
Fluorination
Substitution reactions
Electrons

Keywords

  • buckybowls
  • crystal engineering
  • fluorine
  • pi interactions
  • sumanene

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Schmidt, B. M., Topolinski, B., Higashibayashi, S., Kojima, T., Kawano, M., Lentz, D., & Sakurai, H. (2013). The synthesis of hexafluorosumanene and its congeners. Chemistry - A European Journal, 19(10), 3282-3286. https://doi.org/10.1002/chem.201204622

The synthesis of hexafluorosumanene and its congeners. / Schmidt, Bernd M.; Topolinski, Berit; Higashibayashi, Shuhei; Kojima, Tatsuhiro; Kawano, Masaki; Lentz, Dieter; Sakurai, Hidehiro.

In: Chemistry - A European Journal, Vol. 19, No. 10, 04.03.2013, p. 3282-3286.

Research output: Contribution to journalArticle

Schmidt, BM, Topolinski, B, Higashibayashi, S, Kojima, T, Kawano, M, Lentz, D & Sakurai, H 2013, 'The synthesis of hexafluorosumanene and its congeners', Chemistry - A European Journal, vol. 19, no. 10, pp. 3282-3286. https://doi.org/10.1002/chem.201204622
Schmidt BM, Topolinski B, Higashibayashi S, Kojima T, Kawano M, Lentz D et al. The synthesis of hexafluorosumanene and its congeners. Chemistry - A European Journal. 2013 Mar 4;19(10):3282-3286. https://doi.org/10.1002/chem.201204622
Schmidt, Bernd M. ; Topolinski, Berit ; Higashibayashi, Shuhei ; Kojima, Tatsuhiro ; Kawano, Masaki ; Lentz, Dieter ; Sakurai, Hidehiro. / The synthesis of hexafluorosumanene and its congeners. In: Chemistry - A European Journal. 2013 ; Vol. 19, No. 10. pp. 3282-3286.
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