The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt; Berit Topolinski; Shuhei Higashibayashi; Tatsuhiro Kojima; Masaki Kawano; Dieter Lentz; Hidehiro Sakurai

doi:10.1002/chem.201204622

The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt, Berit Topolinski, Shuhei Higashibayashi, Tatsuhiro Kojima, Masaki Kawano, Dieter Lentz, Hidehiro Sakurai

Research output: Contribution to journal › Article

26 Citations (Scopus)

Abstract

Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

Original language	English
Pages (from-to)	3282-3286
Number of pages	5
Journal	Chemistry - A European Journal
Volume	19
Issue number	10
DOIs	https://doi.org/10.1002/chem.201204622
Publication status	Published - 2013 Mar 4
Externally published	Yes

Keywords

buckybowls
crystal engineering
fluorine
pi interactions
sumanene

ASJC Scopus subject areas

Catalysis
Organic Chemistry

Access to Document

10.1002/chem.201204622

Fingerprint Dive into the research topics of 'The synthesis of hexafluorosumanene and its congeners'. Together they form a unique fingerprint.

Cite this

Schmidt, B. M., Topolinski, B., Higashibayashi, S., Kojima, T., Kawano, M., Lentz, D., & Sakurai, H. (2013). The synthesis of hexafluorosumanene and its congeners. Chemistry - A European Journal, 19(10), 3282-3286. https://doi.org/10.1002/chem.201204622

@article{3379c8f2273f4df2a0da57bb03ee8d12,

title = "The synthesis of hexafluorosumanene and its congeners",

abstract = "Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.",

keywords = "buckybowls, crystal engineering, fluorine, pi interactions, sumanene",

author = "Schmidt, {Bernd M.} and Berit Topolinski and Shuhei Higashibayashi and Tatsuhiro Kojima and Masaki Kawano and Dieter Lentz and Hidehiro Sakurai",

year = "2013",

month = mar,

day = "4",

doi = "10.1002/chem.201204622",

language = "English",

volume = "19",

pages = "3282--3286",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-VCH Verlag",

number = "10",

}

TY - JOUR

T1 - The synthesis of hexafluorosumanene and its congeners

AU - Schmidt, Bernd M.

AU - Topolinski, Berit

AU - Higashibayashi, Shuhei

AU - Kojima, Tatsuhiro

AU - Kawano, Masaki

AU - Lentz, Dieter

AU - Sakurai, Hidehiro

PY - 2013/3/4

Y1 - 2013/3/4

N2 - Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

AB - Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

KW - buckybowls

KW - crystal engineering

KW - fluorine

KW - pi interactions

KW - sumanene

UR - http://www.scopus.com/inward/record.url?scp=84874422588&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84874422588&partnerID=8YFLogxK

U2 - 10.1002/chem.201204622

DO - 10.1002/chem.201204622

M3 - Article

C2 - 23401124

AN - SCOPUS:84874422588

VL - 19

SP - 3282

EP - 3286

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 10

ER -