The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt; Berit Topolinski; Shuhei Higashibayashi; Tatsuhiro Kojima; Masaki Kawano; Dieter Lentz; Hidehiro Sakurai

doi:10.1002/chem.201204622

The synthesis of hexafluorosumanene and its congeners

Bernd M. Schmidt, Berit Topolinski, Shuhei Higashibayashi, Tatsuhiro Kojima, Masaki Kawano, Dieter Lentz, Hidehiro Sakurai

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

Original language	English
Pages (from-to)	3282-3286
Number of pages	5
Journal	Chemistry - A European Journal
Volume	19
Issue number	10
DOIs	https://doi.org/10.1002/chem.201204622
Publication status	Published - 2013 Mar 4
Externally published	Yes

Keywords

buckybowls
crystal engineering
fluorine
pi interactions
sumanene

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/chem.201204622

Cite this

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AU - Topolinski, Berit

AU - Higashibayashi, Shuhei

AU - Kojima, Tatsuhiro

AU - Kawano, Masaki

AU - Lentz, Dieter

AU - Sakurai, Hidehiro

PY - 2013/3/4

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AB - Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.

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KW - crystal engineering

KW - fluorine

KW - pi interactions

KW - sumanene

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The synthesis of hexafluorosumanene and its congeners

Abstract

Keywords

ASJC Scopus subject areas

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