The use of 2,6-anhydro-2-thio glycopyranosyl fluoride for a highly α-stereoselective glycosylation

Kazunobu Toshima, Satsuki Mukaiyama, Takashi Ishiyama, Kuniaki Tatsuta

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The glycosylation of 2, 6-anhydro-1-f1uoro-2-thioglycoside 1 with alcohols under various conditions proceeded smoothly at low temperature to give the corresponding α-glycosides in high yields, and the selectivity was highly independent on the conditions examined.

Original languageEnglish
Pages (from-to)6361-6362
Number of pages2
JournalTetrahedron Letters
Volume31
Issue number44
DOIs
Publication statusPublished - 1990

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Thioglycosides
Glycosylation
Glycosides
Fluorides
Alcohols
Temperature

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

The use of 2,6-anhydro-2-thio glycopyranosyl fluoride for a highly α-stereoselective glycosylation. / Toshima, Kazunobu; Mukaiyama, Satsuki; Ishiyama, Takashi; Tatsuta, Kuniaki.

In: Tetrahedron Letters, Vol. 31, No. 44, 1990, p. 6361-6362.

Research output: Contribution to journalArticle

Toshima, Kazunobu ; Mukaiyama, Satsuki ; Ishiyama, Takashi ; Tatsuta, Kuniaki. / The use of 2,6-anhydro-2-thio glycopyranosyl fluoride for a highly α-stereoselective glycosylation. In: Tetrahedron Letters. 1990 ; Vol. 31, No. 44. pp. 6361-6362.
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