Abstract
This study is an addendum to two previous papers which contained data on the thermal conductivity of the systems H//2-N//2 and N//2-CH//4. The present system is CH//4-CO//2, thus forming a natural progression in the complexity of the molecular structure of the set of binary systems under investigation. The system chosen for study is still characterized by nearly spherical intermolecular force potentials. The results extrapolated to zero density show excellent agreement with the Monchick-Pereira-Mason theory and continue to demonstrate that the inelastic-collision term is small (approximately 1%), thus asserting that the Hirschfelder-Eucken approximation is acceptable. At higher densities, the version of the Thorne-Enskog theory due to E. A. Mason et al. gives a systematic deviation of only minus 2% over the whole composition range.
| Original language | English |
|---|---|
| Pages (from-to) | 945-948 |
| Number of pages | 4 |
| Journal | Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics |
| Volume | 86 |
| Issue number | 10 |
| Publication status | Published - 1982 Oct |
| Externally published | Yes |
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ASJC Scopus subject areas
- Chemical Engineering(all)
Cite this
THERMAL CONDUCTIVITY OF MIXTURES OF METHANE WITH CARBON DIOXIDE. / Kestin, J.; Ro, S. T.; Nagasaka, Yuji.
In: Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, Vol. 86, No. 10, 10.1982, p. 945-948.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - THERMAL CONDUCTIVITY OF MIXTURES OF METHANE WITH CARBON DIOXIDE.
AU - Kestin, J.
AU - Ro, S. T.
AU - Nagasaka, Yuji
PY - 1982/10
Y1 - 1982/10
N2 - This study is an addendum to two previous papers which contained data on the thermal conductivity of the systems H//2-N//2 and N//2-CH//4. The present system is CH//4-CO//2, thus forming a natural progression in the complexity of the molecular structure of the set of binary systems under investigation. The system chosen for study is still characterized by nearly spherical intermolecular force potentials. The results extrapolated to zero density show excellent agreement with the Monchick-Pereira-Mason theory and continue to demonstrate that the inelastic-collision term is small (approximately 1%), thus asserting that the Hirschfelder-Eucken approximation is acceptable. At higher densities, the version of the Thorne-Enskog theory due to E. A. Mason et al. gives a systematic deviation of only minus 2% over the whole composition range.
AB - This study is an addendum to two previous papers which contained data on the thermal conductivity of the systems H//2-N//2 and N//2-CH//4. The present system is CH//4-CO//2, thus forming a natural progression in the complexity of the molecular structure of the set of binary systems under investigation. The system chosen for study is still characterized by nearly spherical intermolecular force potentials. The results extrapolated to zero density show excellent agreement with the Monchick-Pereira-Mason theory and continue to demonstrate that the inelastic-collision term is small (approximately 1%), thus asserting that the Hirschfelder-Eucken approximation is acceptable. At higher densities, the version of the Thorne-Enskog theory due to E. A. Mason et al. gives a systematic deviation of only minus 2% over the whole composition range.
UR - http://www.scopus.com/inward/record.url?scp=0020194150&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0020194150&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0020194150
VL - 86
SP - 945
EP - 948
JO - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
JF - Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
SN - 0005-9021
IS - 10
ER -