THERMAL CONDUCTIVITY OF MIXTURES OF METHANE WITH CARBON DIOXIDE.

J. Kestin, S. T. Ro, Yuji Nagasaka

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

This study is an addendum to two previous papers which contained data on the thermal conductivity of the systems H//2-N//2 and N//2-CH//4. The present system is CH//4-CO//2, thus forming a natural progression in the complexity of the molecular structure of the set of binary systems under investigation. The system chosen for study is still characterized by nearly spherical intermolecular force potentials. The results extrapolated to zero density show excellent agreement with the Monchick-Pereira-Mason theory and continue to demonstrate that the inelastic-collision term is small (approximately 1%), thus asserting that the Hirschfelder-Eucken approximation is acceptable. At higher densities, the version of the Thorne-Enskog theory due to E. A. Mason et al. gives a systematic deviation of only minus 2% over the whole composition range.

Original languageEnglish
Pages (from-to)945-948
Number of pages4
JournalBerichte der Bunsengesellschaft/Physical Chemistry Chemical Physics
Volume86
Issue number10
Publication statusPublished - 1982 Oct
Externally publishedYes

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Methane
Carbon Monoxide
Carbon Dioxide
Molecular structure
Thermal conductivity
Carbon dioxide
Chemical analysis

ASJC Scopus subject areas

  • Chemical Engineering(all)

Cite this

THERMAL CONDUCTIVITY OF MIXTURES OF METHANE WITH CARBON DIOXIDE. / Kestin, J.; Ro, S. T.; Nagasaka, Yuji.

In: Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics, Vol. 86, No. 10, 10.1982, p. 945-948.

Research output: Contribution to journalArticle

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