Total Synthesis And Absolute Configuration Of Sphingofungin D (N-Acetyl Asperfungin)

Noritaka Chida; Hiroyuki ikemoto; Aino Noguchi; Pilar Seiji Amano; Seiichiro Ogawa

doi:10.1080/10575639508043174

Total Synthesis And Absolute Configuration Of Sphingofungin D (N-Acetyl Asperfungin)

Noritaka Chida, Hiroyuki ikemoto, Aino Noguchi, Pilar Seiji Amano, Seiichiro Ogawa

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

The total synthesis ot an antifungal novel amino acid derivative, sphingofungin D (N-acetyl asperfungin) starting from myoinositol and (fl)-epoxyoctane is described. This synthetic study showed that the undetermined stereochemistry at C-14 in sphingofungins should be R.

Original language	English
Pages (from-to)	295-302
Number of pages	8
Journal	Natural Product Letters
Volume	6
Issue number	4
DOIs	https://doi.org/10.1080/10575639508043174
Publication status	Published - 1995 Jun 1
Externally published	Yes

Keywords

(R)-Epoxyoctane
Absolute Configuration
Asperfungin
Sphingofungins
myoinositol

ASJC Scopus subject areas

Molecular Medicine

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10.1080/10575639508043174

Cite this

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abstract = "The total synthesis ot an antifungal novel amino acid derivative, sphingofungin D (N-acetyl asperfungin) starting from myoinositol and (fl)-epoxyoctane is described. This synthetic study showed that the undetermined stereochemistry at C-14 in sphingofungins should be R.",

keywords = "(R)-Epoxyoctane, Absolute Configuration, Asperfungin, Sphingofungins, myoinositol",

author = "Noritaka Chida and Hiroyuki ikemoto and Aino Noguchi and {Seiji Amano}, Pilar and Seiichiro Ogawa",

year = "1995",

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AU - Chida, Noritaka

AU - ikemoto, Hiroyuki

AU - Noguchi, Aino

AU - Seiji Amano, Pilar

AU - Ogawa, Seiichiro

PY - 1995/6/1

Y1 - 1995/6/1

N2 - The total synthesis ot an antifungal novel amino acid derivative, sphingofungin D (N-acetyl asperfungin) starting from myoinositol and (fl)-epoxyoctane is described. This synthetic study showed that the undetermined stereochemistry at C-14 in sphingofungins should be R.

AB - The total synthesis ot an antifungal novel amino acid derivative, sphingofungin D (N-acetyl asperfungin) starting from myoinositol and (fl)-epoxyoctane is described. This synthetic study showed that the undetermined stereochemistry at C-14 in sphingofungins should be R.

KW - (R)-Epoxyoctane

KW - Absolute Configuration

KW - Asperfungin

KW - Sphingofungins

KW - myoinositol

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ER -

Total Synthesis And Absolute Configuration Of Sphingofungin D (N-Acetyl Asperfungin)

Abstract

Keywords

ASJC Scopus subject areas

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