Total synthesis of (+)-(1,2,3/4,5)-2,3,4,5-tetrahydroxycyclohexane-1-methanol and (+)-(1,3/2,4,5)-5-amino-2,3,4-trihydroxycyclohexane-1 -methanol [(+)-validamine]. x-ray crystal structure of (3S)-(+)-2-exo-bromo-4,8-dioxatricyclo[4.2.1.03,7]nonan-5-one

Seiichiro Ogawa, Yoshikazu Iwasawa, Taisuke Nose, Tetsuo Suami, Shigeru Ohba, Masatoki Ito, Yoshihiko Saito

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Chemical Compounds