Total synthesis of (±)-5-deoxystrigol via reductive carbon-carbon bond formation

Mitsuru Shoji; Eriko Suzuki; Minoru Ueda

doi:10.1021/jo9002085

Total synthesis of (±)-5-deoxystrigol via reductive carbon-carbon bond formation

Mitsuru Shoji, Eriko Suzuki, Minoru Ueda

School of Pharmaceutical Sciences

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

(Chemical Equation Presented) The total synthesis of 5-deoxystrigol was successfully carried out via the regioselective coupling reaction between the aluminum ate complex of an alkyne and an epoxide and the two reductive carbon-carbon bond formations in the presence of transition metals as key steps.

Original language	English
Pages (from-to)	3966-3969
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	74
Issue number	10
DOIs	https://doi.org/10.1021/jo9002085
Publication status	Published - 2009 May 15

ASJC Scopus subject areas

Organic Chemistry

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title = "Total synthesis of (±)-5-deoxystrigol via reductive carbon-carbon bond formation",

abstract = "(Chemical Equation Presented) The total synthesis of 5-deoxystrigol was successfully carried out via the regioselective coupling reaction between the aluminum ate complex of an alkyne and an epoxide and the two reductive carbon-carbon bond formations in the presence of transition metals as key steps.",

author = "Mitsuru Shoji and Eriko Suzuki and Minoru Ueda",

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AU - Shoji, Mitsuru

AU - Suzuki, Eriko

AU - Ueda, Minoru

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Y1 - 2009/5/15

N2 - (Chemical Equation Presented) The total synthesis of 5-deoxystrigol was successfully carried out via the regioselective coupling reaction between the aluminum ate complex of an alkyne and an epoxide and the two reductive carbon-carbon bond formations in the presence of transition metals as key steps.

AB - (Chemical Equation Presented) The total synthesis of 5-deoxystrigol was successfully carried out via the regioselective coupling reaction between the aluminum ate complex of an alkyne and an epoxide and the two reductive carbon-carbon bond formations in the presence of transition metals as key steps.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

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Total synthesis of (±)-5-deoxystrigol via reductive carbon-carbon bond formation

Abstract

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