Total synthesis of (-)-anisatin

Akihiro Ogura; Kohei Yamada; Satoshi Yokoshima; Tohru Fukuyama

doi:10.1021/ol300390k

Total synthesis of (-)-anisatin

Akihiro Ogura, Kohei Yamada, Satoshi Yokoshima, Tohru Fukuyama

Research output: Contribution to journal › Article › peer-review

39 Citations (Scopus)

Abstract

A novel synthetic route to (-)-anisatin has been developed. Our synthesis features a rhodium-catalyzed 1,4-addition of an arylboronic acid, an intramolecular Diels-Alder reaction of an ortho-quinone monoketal, a stereoselective [2,3]-Wittig rearrangement, and construction of the oxabicyclo [3.3.1] skeleton via cleavage of an epoxide by a primary amide.

Original language	English
Pages (from-to)	1632-1635
Number of pages	4
Journal	Organic Letters
Volume	14
Issue number	6
DOIs	https://doi.org/10.1021/ol300390k
Publication status	Published - 2012 Mar 16
Externally published	Yes

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol300390k

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author = "Akihiro Ogura and Kohei Yamada and Satoshi Yokoshima and Tohru Fukuyama",

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AU - Ogura, Akihiro

AU - Yamada, Kohei

AU - Yokoshima, Satoshi

AU - Fukuyama, Tohru

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Y1 - 2012/3/16

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Total synthesis of (-)-anisatin

Abstract

ASJC Scopus subject areas

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