Total synthesis of spicamycin amino nucleoside

Tamotsu Suzuki, Sayaka Tanaka, Iwao Yamada, Yoshiaki Koashi, Kazue Yamada, Noritaka Chida

Research output: Contribution to journalArticlepeer-review

33 Citations (Scopus)

Abstract

The first total synthesis of spicamycin amino nucleoside 2 has been achieved. The aminoheptose unit 5 was prepared stereoselectively from myo-inositol, and the characteristic N-glycoside linkage was constructed by way of Pd-catalyzed coupling reaction of 5 with 6-chloropurine derivative 6.

Original languageEnglish
Pages (from-to)1137-1140
Number of pages4
JournalOrganic Letters
Volume2
Issue number8
DOIs
Publication statusPublished - 2000 Apr 20

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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