@article{4e390051dcbe4a6bb5b371c2313e61ae,
title = "Total Synthesis of Tunicamycin v",
abstract = "The total synthesis of tunicamycin V is described. This strategy is based on the initial construction of tunicaminyluracil, which is regarded to play an important role in the observed biological activities. The key to the synthesis was a Mukaiyama aldol reaction followed by a furan-oxidation to construct the undecose skeleton, a [3,3] sigmatropic rearrangement of a cyanate, and a highly selective trehalose-type glycosylation.",
author = "Kazuki Yamamoto and Fumika Yakushiji and Takanori Matsumaru and Satoshi Ichikawa",
note = "Funding Information: We wish to thank Ms. S. Oka (Center for Instrumental Analysis, Hokkaido University) for measurement of the mass spectra. This research was supported by JSPS Grant-in-Aid for Scientific Research (B) (to S.I., Grant Number 16H05097) and by Astellas Foundation for Research on Metabolic Disorders and partly supported by Hokkaido University, Global Facility Center (GFC), Pharma Science Open Unit (PSOU), funded by MEXT under “Support Program for Implementation of New Equipment Sharing System”, the Platform Project for Supporting Drug Discovery and Life Science Research (Basis for Supporting Innovative Drug Discovery and Life Science Research; BINDS) from the Japan Agency for Medical Research and Development (AMED). Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",
year = "2018",
month = jan,
day = "5",
doi = "10.1021/acs.orglett.7b03623",
language = "English",
volume = "20",
pages = "256--259",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "1",
}