Trans-Bis(2,2-diphenylethylamine-κN)bis(5,5-diphenylhydantoinato- κN3)copper(II) and its chloroform disolvate

Takashiro Akitsu, Yasuaki Einaga

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19 Citations (Scopus)

Abstract

The crystal structures of the title compounds, [Cu(C15H 11N2-O2)2(C14H 15N)2] and [Cu(C15H11N 2O2)2(C14H15N) 2]·2CHCl3, respectively, have been determined. The red disolvate complex affords a square-planar CuN4 coordination environment in which the Cu" atom lies on a centre of symmetry. The blue solvent-free complex affords a distorted square-pyramidal CuN4O coordination environment and adjacent molecules form centrosymmetric dimers. A comparison of the different crystal structures focuses on the role of the solvent molecules in supramolecular assemblies of the copper(II) complexes.

Original languageEnglish
Pages (from-to)m183-m186
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume61
Issue number4
DOIs
Publication statusPublished - 2005 Apr 1

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ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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