TY - JOUR
T1 - Trans-Bis(4-aminopyridine-κN)bis(succinimidato-κN)copper(II) dihydrate
AU - Akitsu, Takashiro
AU - Einaga, Yasuaki
PY - 2006/3/1
Y1 - 2006/3/1
N2 - The title compound, [Cu(C4H4NO2) 2(C5H6N2)2] ·2H2O has its metal atom in a square-planar trans-[CuN 4] coordination environment; the CuII atom lies on a center of symmetry. Both succinimidate and 4-aminopyridine ligands behave as monodentate ligands, which coordinate through deprotonated imidate and pyridine (not amino) N atoms, respectively. The 4-aminopyridine is the first ligand in such CuII complexes containing two different N atoms to take potentially different coordination modes.
AB - The title compound, [Cu(C4H4NO2) 2(C5H6N2)2] ·2H2O has its metal atom in a square-planar trans-[CuN 4] coordination environment; the CuII atom lies on a center of symmetry. Both succinimidate and 4-aminopyridine ligands behave as monodentate ligands, which coordinate through deprotonated imidate and pyridine (not amino) N atoms, respectively. The 4-aminopyridine is the first ligand in such CuII complexes containing two different N atoms to take potentially different coordination modes.
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U2 - 10.1107/S1600536806006209
DO - 10.1107/S1600536806006209
M3 - Article
AN - SCOPUS:33644917130
SN - 1600-5368
VL - 62
SP - m625-m627
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 3
ER -