trans-bis(acetylacetonato-O,O′)(3-methyl-pyridine-N)nitrocobalt(III)

Hiroki Miyazaki; Masanobu Tsuchimoto; Shigeru Ohba

doi:10.1107/S0108270197012699

trans-bis(acetylacetonato-O,O′)(3-methyl-pyridine-N)nitrocobalt(III)

Hiroki Miyazaki, Masanobu Tsuchimoto, Shigeru Ohba

Department of Humanities and Social Sciences

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The crystal structure determination of the title compound, [Co(C₅H₇O₂)₂(NO₂)(C ₆H₇N)], shows that the coordination geometry around the Co^III atom is slightly distorted octahedral, with a Co-NO₂ bond distance of 1.905 (3) Å. The crystal is photostable, which may be due to the narrow cavity around the nitro group.

Original language	English
Pages (from-to)	46-47
Number of pages	2
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	1
DOIs	https://doi.org/10.1107/S0108270197012699
Publication status	Published - 1998 Jan 15

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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title = "trans-bis(acetylacetonato-O,O′)(3-methyl-pyridine-N)nitrocobalt(III)",

abstract = "The crystal structure determination of the title compound, [Co(C5H7O2)2(NO2)(C 6H7N)], shows that the coordination geometry around the CoIII atom is slightly distorted octahedral, with a Co-NO2 bond distance of 1.905 (3) {\AA}. The crystal is photostable, which may be due to the narrow cavity around the nitro group.",

author = "Hiroki Miyazaki and Masanobu Tsuchimoto and Shigeru Ohba",

year = "1998",

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doi = "10.1107/S0108270197012699",

language = "English",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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T1 - trans-bis(acetylacetonato-O,O′)(3-methyl-pyridine-N)nitrocobalt(III)

AU - Miyazaki, Hiroki

AU - Tsuchimoto, Masanobu

AU - Ohba, Shigeru

PY - 1998/1/15

Y1 - 1998/1/15

N2 - The crystal structure determination of the title compound, [Co(C5H7O2)2(NO2)(C 6H7N)], shows that the coordination geometry around the CoIII atom is slightly distorted octahedral, with a Co-NO2 bond distance of 1.905 (3) Å. The crystal is photostable, which may be due to the narrow cavity around the nitro group.

AB - The crystal structure determination of the title compound, [Co(C5H7O2)2(NO2)(C 6H7N)], shows that the coordination geometry around the CoIII atom is slightly distorted octahedral, with a Co-NO2 bond distance of 1.905 (3) Å. The crystal is photostable, which may be due to the narrow cavity around the nitro group.

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trans-bis(acetylacetonato-O,O′)(3-methyl-pyridine-N)nitrocobalt(III)

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