Transition dipole-moment of the ν13 band of acetylene measured with dual-comb Fourier-transform spectroscopy

Sho Okubo, Kana Iwakuni, Koichi M.T. Yamada, Hajime Inaba, Atsushi Onae, Feng Lei Hong, Hiroyuki Sasada

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5 Citations (Scopus)

Abstract

The ν13 vibration band of acetylene (C2H2) in the near infrared region was recorded with a dual-comb Fourier-transform spectrometer. We observed 56 transitions from P(26) to R(29) at six different column densities. The integral line intensity was determined for each recorded absorption line by fitting the line profile to Lambert-Beer's law with a Voigt function. Thanks to the outstanding capability of dual-comb spectroscopy to cover a broad spectrum in a relatively short time with high resolution and high frequency precision, we determined the reliable line strength for each ro-vibrational transition as well as the transition dipole moment for this band.

Original languageEnglish
Pages (from-to)10-16
Number of pages7
JournalJournal of Molecular Spectroscopy
Volume341
DOIs
Publication statusPublished - 2017 Nov 1

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Keywords

  • Acetylene
  • Dual-comb spectroscopy
  • Fourier-transform spectroscopy
  • Line strength
  • Near infrared
  • Transition dipole-moment

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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