Transparent Zero-Birefringence Polymers

Shuichi Iwata, Hisashi Tsukahara, Eisuke Nihei, Yasuhiro Koike

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

Birefringence is caused by orientation of polymer chains during injection-molding and extrusion and it is a disadvantage in optical systems such as lenses, compact disks, waveguides. We propose new transparent zero-birefringence polymers for any degree of orientation of polymer chains, which are obtained by the following two methods. One is random copolymerization of negatively and positively birefringent monomers. The other is doping of a small amount of large anisotropic molecules into a polymer matrix to compensate the birefringence caused by the orientation of polymer chains. Zero-birefringence polymers synthesized by these two methods have low scattering loss, which is comparable with that of pure poly(methyl methacrylate) (PMMA), and had no observable microscopic heterogeneous structures.

Original languageEnglish
Pages (from-to)16-29
Number of pages14
JournalACS Symposium Series
Volume672
Publication statusPublished - 1997

Fingerprint

Birefringence
Polymers
Polymethyl Methacrylate
Polymer matrix
Polymethyl methacrylates
Injection molding
Optical systems
Copolymerization
Extrusion
Lenses
Waveguides
Monomers
Doping (additives)
Scattering
Molecules

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Transparent Zero-Birefringence Polymers. / Iwata, Shuichi; Tsukahara, Hisashi; Nihei, Eisuke; Koike, Yasuhiro.

In: ACS Symposium Series, Vol. 672, 1997, p. 16-29.

Research output: Contribution to journalArticle

Iwata, S, Tsukahara, H, Nihei, E & Koike, Y 1997, 'Transparent Zero-Birefringence Polymers', ACS Symposium Series, vol. 672, pp. 16-29.
Iwata, Shuichi ; Tsukahara, Hisashi ; Nihei, Eisuke ; Koike, Yasuhiro. / Transparent Zero-Birefringence Polymers. In: ACS Symposium Series. 1997 ; Vol. 672. pp. 16-29.
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