Triplet exciton fusion at dislocations in anthracene

K. Yokoi, Y. Ohba

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The fusion reaction of triplet excitons trapped at edge dislocations (001)[010] was studied in anthracene crystals by observing delayed fluorescence. The fusion rate obtained by kinetic analysis which includes the exciton-trapping effect is about unity measured in cm3 s -1, which is much greater than the fusion rate of free excitons (≅4×10-12 cm3 s-1), and also greater than an estimation based on the diffusion transport of trapped excitons along the dislocation line. The fusion mechanism of a pair of trapped excitons must be dominated by some long-range interaction.

Original languageEnglish
Pages (from-to)1887-1891
Number of pages5
JournalThe Journal of Chemical Physics
Volume87
Issue number3
DOIs
Publication statusPublished - 1987 Jan 1

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Triplet exciton fusion at dislocations in anthracene'. Together they form a unique fingerprint.

Cite this