Two-dimensional octacyano-bridged Mn(II)-Nb(IV) bimetal assembly with four different configurations of 3-hydroxypyridines

Daisuke Takahashi; Koji Nakabayashi; Shu Tanaka; Shin Ichi Ohkoshi

doi:10.1016/j.inoche.2012.09.021

Two-dimensional octacyano-bridged Mn(II)-Nb(IV) bimetal assembly with four different configurations of 3-hydroxypyridines

Daisuke Takahashi, Koji Nakabayashi, Shu Tanaka, Shin Ichi Ohkoshi

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

We report the crystal structure and magnetic properties of a two-dimensional cyano-bridged Mn^II(S = 5/2)-Nb^IV(S = 1/2) bimetal assembly (1), and the magnetic properties of an isostructural cyano-bridged Mn^II-Mo^IV(S = 0) bimetal assembly (2). 1 contains 3-hydroxypyridine ligands with four types of coordination arrangements, includes μ-oxo-bridged Mn-Mn sites, and shows ferrimagnetism with a Curie temperature of 16 K due to the antiferromagnetic Mn^II-Nb^IV superexchange interaction through the cyano groups. 2 exhibits paramagnetism with the antiferromagnetic interaction between Mn and Mn through the μ-oxo-bridges.

Original language	English
Pages (from-to)	47-50
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	27
DOIs	https://doi.org/10.1016/j.inoche.2012.09.021
Publication status	Published - 2013 Jan
Externally published	Yes

Keywords

Antiferromagnetic superexchange interaction
Cyano-bridged bimetal assembly
Ferrimagnetism
Manganese
Niobium
Octacyanoniobate

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.inoche.2012.09.021

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title = "Two-dimensional octacyano-bridged Mn(II)-Nb(IV) bimetal assembly with four different configurations of 3-hydroxypyridines",

abstract = "We report the crystal structure and magnetic properties of a two-dimensional cyano-bridged MnII(S = 5/2)-NbIV(S = 1/2) bimetal assembly (1), and the magnetic properties of an isostructural cyano-bridged MnII-MoIV(S = 0) bimetal assembly (2). 1 contains 3-hydroxypyridine ligands with four types of coordination arrangements, includes μ-oxo-bridged Mn-Mn sites, and shows ferrimagnetism with a Curie temperature of 16 K due to the antiferromagnetic MnII-NbIV superexchange interaction through the cyano groups. 2 exhibits paramagnetism with the antiferromagnetic interaction between Mn and Mn through the μ-oxo-bridges.",

keywords = "Antiferromagnetic superexchange interaction, Cyano-bridged bimetal assembly, Ferrimagnetism, Manganese, Niobium, Octacyanoniobate",

author = "Daisuke Takahashi and Koji Nakabayashi and Shu Tanaka and Ohkoshi, {Shin Ichi}",

note = "Funding Information: The present research was supported partly by the CREST program of JST , a Grant-in-Aid for Young Scientists (S) from JSPS , the Global COE Program “Chemistry Innovation through Cooperation of Science and Engineering”, Advanced Phonon Science Alliance (APSA) from MEXT Japan , the Asahi Glass Foundation , the Center for Nano Lithography & Analysis , The University of Tokyo , supported by MEXT Japan, and the Photon Factory Program Advisory Committee ( 2009G678 ). S. T. is partially supported by Grand-in-Aid for JSPS Fellows (23–7601). ",

year = "2013",

month = jan,

doi = "10.1016/j.inoche.2012.09.021",

language = "English",

volume = "27",

pages = "47--50",

journal = "Inorganic Chemistry Communication",

issn = "1387-7003",

publisher = "Elsevier BV",

}

TY - JOUR

T1 - Two-dimensional octacyano-bridged Mn(II)-Nb(IV) bimetal assembly with four different configurations of 3-hydroxypyridines

AU - Takahashi, Daisuke

AU - Nakabayashi, Koji

AU - Tanaka, Shu

AU - Ohkoshi, Shin Ichi

N1 - Funding Information: The present research was supported partly by the CREST program of JST , a Grant-in-Aid for Young Scientists (S) from JSPS , the Global COE Program “Chemistry Innovation through Cooperation of Science and Engineering”, Advanced Phonon Science Alliance (APSA) from MEXT Japan , the Asahi Glass Foundation , the Center for Nano Lithography & Analysis , The University of Tokyo , supported by MEXT Japan, and the Photon Factory Program Advisory Committee ( 2009G678 ). S. T. is partially supported by Grand-in-Aid for JSPS Fellows (23–7601).

PY - 2013/1

Y1 - 2013/1

N2 - We report the crystal structure and magnetic properties of a two-dimensional cyano-bridged MnII(S = 5/2)-NbIV(S = 1/2) bimetal assembly (1), and the magnetic properties of an isostructural cyano-bridged MnII-MoIV(S = 0) bimetal assembly (2). 1 contains 3-hydroxypyridine ligands with four types of coordination arrangements, includes μ-oxo-bridged Mn-Mn sites, and shows ferrimagnetism with a Curie temperature of 16 K due to the antiferromagnetic MnII-NbIV superexchange interaction through the cyano groups. 2 exhibits paramagnetism with the antiferromagnetic interaction between Mn and Mn through the μ-oxo-bridges.

AB - We report the crystal structure and magnetic properties of a two-dimensional cyano-bridged MnII(S = 5/2)-NbIV(S = 1/2) bimetal assembly (1), and the magnetic properties of an isostructural cyano-bridged MnII-MoIV(S = 0) bimetal assembly (2). 1 contains 3-hydroxypyridine ligands with four types of coordination arrangements, includes μ-oxo-bridged Mn-Mn sites, and shows ferrimagnetism with a Curie temperature of 16 K due to the antiferromagnetic MnII-NbIV superexchange interaction through the cyano groups. 2 exhibits paramagnetism with the antiferromagnetic interaction between Mn and Mn through the μ-oxo-bridges.

KW - Antiferromagnetic superexchange interaction

KW - Cyano-bridged bimetal assembly

KW - Ferrimagnetism

KW - Manganese

KW - Niobium

KW - Octacyanoniobate

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DO - 10.1016/j.inoche.2012.09.021

M3 - Article

AN - SCOPUS:84868650442

SN - 1387-7003

VL - 27

SP - 47

EP - 50

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

ER -

Two-dimensional octacyano-bridged Mn(II)-Nb(IV) bimetal assembly with four different configurations of 3-hydroxypyridines

Abstract

Keywords

ASJC Scopus subject areas

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