Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform

Yujiro Hayashi, Mitsuhiro Takeda, Mitsuru Shoji, Masataka Morita

Research output: Contribution to journalArticle

Abstract

Dramatic acceleration of the Diels-Alder reaction of acrylate ester or methacrolein with cyclopentadiene has been observed under ultracentrifugation conditions in the presence of water, when water-CHCl3 two-phase system was employed. The Diels-Alder reaction proceeds in the lower organic phase under ultracentrifugation-induced high pressure with the upper water phase acting like a weight.

Original languageEnglish
Pages (from-to)68-69
Number of pages2
JournalChemistry Letters
Volume36
Issue number1
DOIs
Publication statusPublished - 2007 Jan 5
Externally publishedYes

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Chloroform
Water
Cyclopentanes
Esters
Ultracentrifugation

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform. / Hayashi, Yujiro; Takeda, Mitsuhiro; Shoji, Mitsuru; Morita, Masataka.

In: Chemistry Letters, Vol. 36, No. 1, 05.01.2007, p. 68-69.

Research output: Contribution to journalArticle

Hayashi, Yujiro ; Takeda, Mitsuhiro ; Shoji, Mitsuru ; Morita, Masataka. / Ultracentrifuge-mediated Diels-Alder reaction in a two-phase system of water and chloroform. In: Chemistry Letters. 2007 ; Vol. 36, No. 1. pp. 68-69.
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