Abstract
A new approach to 3-acetoxy-2-methyl-2-vinylcyclohexanone and 3-acetoxy-2-methyl-2-vinylcyclopentanone in stereochemically pure state, by means of a combination of yeast-catalyzed reduction and subsequent radical β-fragmentation is described.
| Original language | English |
|---|---|
| Pages (from-to) | 1763-1767 |
| Number of pages | 5 |
| Journal | Tetrahedron Letters |
| Volume | 45 |
| Issue number | 8 |
| DOIs | |
| Publication status | Published - 2004 Feb 16 |
Keywords
- Hydroxyketone
- Radical β-fragmentation
- Substituted cyclohexanone
- Substituted cyclopentanone
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Cite this
Fuhshuku, K. I., Tomita, M., & Sugai, T. (2004). Unprecedented chemo-enzymatic synthesis of stereochemically pure 3-acetoxy-2-methyl-2-vinylcycloalkanones. Tetrahedron Letters, 45(8), 1763-1767. https://doi.org/10.1016/j.tetlet.2003.12.084