Abstract
A new approach to 3-acetoxy-2-methyl-2-vinylcyclohexanone and 3-acetoxy-2-methyl-2-vinylcyclopentanone in stereochemically pure state, by means of a combination of yeast-catalyzed reduction and subsequent radical β-fragmentation is described.
Original language | English |
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Pages (from-to) | 1763-1767 |
Number of pages | 5 |
Journal | Tetrahedron Letters |
Volume | 45 |
Issue number | 8 |
DOIs | |
Publication status | Published - 2004 Feb 16 |
Keywords
- Hydroxyketone
- Radical β-fragmentation
- Substituted cyclohexanone
- Substituted cyclopentanone
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry