Vapor-phase hydrosilylation using a transition metal complex catalyst in a liquid polymer medium supported on silica gel

Masaki Okamoto, Hironari Kiya, Akihiko Matsumura, Eiichi Suzuki

Research output: Contribution to journalArticle

12 Citations (Scopus)

Abstract

Transition metal catalysts in various liquid polymer media supported on silica gel were prepared and used for vapor-phase hydrosilylation. Tetraammineplatinum(II) chloride and potassium hexachloroplatinate(IV) in a polyethylene glycol (PEG) medium showed high and stable activity. Deactivation of the catalyst was not observed unless a high platinum concentration in PEG was used. When the amount of PEG was 40 vol% of the pore volume of silica gel, PEG was coated on the pore walls of the silica gel, and did not block the pore openings. Active species in the PEG were formed only during the reaction.

Original languageEnglish
Pages (from-to)72-79
Number of pages8
JournalCatalysis Letters
Volume123
Issue number1-2
DOIs
Publication statusPublished - 2008 Jun 1
Externally publishedYes

Fingerprint

Hydrosilylation
Coordination Complexes
Silica Gel
Silica gel
silica gel
Metal complexes
Polyethylene glycols
Transition metals
glycols
polyethylenes
Polymers
transition metals
Vapors
vapor phases
catalysts
Catalysts
polymers
Liquids
liquids
porosity

Keywords

  • Hydrosilylation
  • Platinum catalyst
  • Polyethylene glycol
  • Supported liquid phase catalyst

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Catalysis

Cite this

Vapor-phase hydrosilylation using a transition metal complex catalyst in a liquid polymer medium supported on silica gel. / Okamoto, Masaki; Kiya, Hironari; Matsumura, Akihiko; Suzuki, Eiichi.

In: Catalysis Letters, Vol. 123, No. 1-2, 01.06.2008, p. 72-79.

Research output: Contribution to journalArticle

Okamoto, Masaki ; Kiya, Hironari ; Matsumura, Akihiko ; Suzuki, Eiichi. / Vapor-phase hydrosilylation using a transition metal complex catalyst in a liquid polymer medium supported on silica gel. In: Catalysis Letters. 2008 ; Vol. 123, No. 1-2. pp. 72-79.
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