Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic

Guangming Li; Osamu Sato; Takashiro Akitsu; Yasuaki Einaga

doi:10.1016/j.jssc.2004.06.015

Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic

Guangming Li, Osamu Sato, Takashiro Akitsu, Yasuaki Einaga

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A visible light-induced magnetization change of the 3d-4f heterometallic, [Nd(DMF)₄(H₂O)₃(μ-NC)Co(CN) ₅]·H₂O (DMF=N,N-dimethylformamide), is observed and described. The plots of χ_MT versus T of the complex showed that the χ_MT values, after visible light illumination, were enhanced by about 25% as compared to before irradiation in the temperature range of 5-40K.

Original language	English
Pages (from-to)	3835-3838
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	177
Issue number	10
DOIs	https://doi.org/10.1016/j.jssc.2004.06.015
Publication status	Published - 2004 Oct

Keywords

3d-4f complex
Cyano-bridge
Light-induced
Magnetism

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Ceramics and Composites
Condensed Matter Physics
Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jssc.2004.06.015

Cite this

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title = "Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic",

abstract = "A visible light-induced magnetization change of the 3d-4f heterometallic, [Nd(DMF)4(H2O)3(μ-NC)Co(CN) 5]·H2O (DMF=N,N-dimethylformamide), is observed and described. The plots of χMT versus T of the complex showed that the χMT values, after visible light illumination, were enhanced by about 25% as compared to before irradiation in the temperature range of 5-40K.",

keywords = "3d-4f complex, Cyano-bridge, Light-induced, Magnetism",

author = "Guangming Li and Osamu Sato and Takashiro Akitsu and Yasuaki Einaga",

note = "Funding Information: This work is supported by Grant-in-Aid for Scientific Research on Priority Areas (417) and for the 21st century COE program “Keio Life Conjugate Chemistry” from the Ministry of Education, Culture, Sport, Science, and Technology (MEXT) of Japan.",

year = "2004",

month = oct,

doi = "10.1016/j.jssc.2004.06.015",

language = "English",

volume = "177",

pages = "3835--3838",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic

AU - Li, Guangming

AU - Sato, Osamu

AU - Akitsu, Takashiro

AU - Einaga, Yasuaki

N1 - Funding Information: This work is supported by Grant-in-Aid for Scientific Research on Priority Areas (417) and for the 21st century COE program “Keio Life Conjugate Chemistry” from the Ministry of Education, Culture, Sport, Science, and Technology (MEXT) of Japan.

PY - 2004/10

Y1 - 2004/10

N2 - A visible light-induced magnetization change of the 3d-4f heterometallic, [Nd(DMF)4(H2O)3(μ-NC)Co(CN) 5]·H2O (DMF=N,N-dimethylformamide), is observed and described. The plots of χMT versus T of the complex showed that the χMT values, after visible light illumination, were enhanced by about 25% as compared to before irradiation in the temperature range of 5-40K.

AB - A visible light-induced magnetization change of the 3d-4f heterometallic, [Nd(DMF)4(H2O)3(μ-NC)Co(CN) 5]·H2O (DMF=N,N-dimethylformamide), is observed and described. The plots of χMT versus T of the complex showed that the χMT values, after visible light illumination, were enhanced by about 25% as compared to before irradiation in the temperature range of 5-40K.

KW - 3d-4f complex

KW - Cyano-bridge

KW - Light-induced

KW - Magnetism

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DO - 10.1016/j.jssc.2004.06.015

M3 - Article

AN - SCOPUS:7244239530

SN - 0022-4596

VL - 177

SP - 3835

EP - 3838

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 10

ER -

Visible light-induced magnetization change of the cyano-bridged 3d-4f heterobimetallic

Abstract

Keywords

ASJC Scopus subject areas

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