Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser

M. Sugawara, K. Yamamoto, Y. Fujimura

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Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.

Original languageEnglish
Pages (from-to)77-82
Number of pages6
JournalJournal of Molecular Structure
Publication statusPublished - 1994 Jan 1


ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Organic Chemistry
  • Inorganic Chemistry

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