Wavepacket dynamics of hydrogen cyanide excited by intense ultrashort pulsed laser

Michihiko Sugawara, K. Yamamoto, Y. Fujimura

Research output: Contribution to journalArticle

Abstract

Dynamics of hydrogen cyanide in the ground electronic state under an intense, impulsive excitation condition is theoretically studied based on the semiclassical theory of the molecule-radiation field interaction. Hydrogen migration in the HCN/HNC system, which originates from a simultaneous, IR-multiphoton absorption induced by such an impulsive excitation, is expressed in terms of the nuclear wavepacket propagation. Dynamic coupling between the CH stretching and HCN bending vibrational modes is shown to play an important role in the hydrogen migration process.

Original languageEnglish
Pages (from-to)77-82
Number of pages6
JournalJournal of Molecular Structure: THEOCHEM
Volume310
DOIs
Publication statusPublished - 1994
Externally publishedYes

ASJC Scopus subject areas

  • Biochemistry
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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